Carbonylation of Ethene Catalysed by Pd(II)-Phosphine Complexes

Autor: Gianni Cavinato, Luigi Toniolo

Publikováno v: Molecules, Vol 19, Iss 9, Pp 15116-15161 (2014)

This review deals with olefin carbonylation catalysed by Pd(II)-phosphine complexes in protic solvents. In particular, the results obtained in the carbonylation with ethene are reviewed. After a short description of the basic concepts relevant to thi

Externí odkaz: https://doaj.org/article/6cb78871b64e429b936180367bde9fb7

Structural analyses of blended Nafion/PVDF electrospun nanofibers

Autor: Enrico Negro, Keti Vezzù, V. Di Noto, Jun Woo Park, Graeme Nawn, Giuseppe Pace, Peter N. Pintauro, Ryszard Wycisk, Gianni Cavinato

Publikováno v: PCCP. Physical chemistry chemical physics
21 (2019): 10357–10369. doi:10.1039/c9cp01891c
info:cnr-pdr/source/autori:Nawn G.; Vezzù K.; Negro E.; Pace G.; Park J.W.; Wycisk R.; Cavinato G.; Pintauro P.N.; Di Noto V./titolo:Structural analyses of blended Nafion%2FPVDF electrospun nanofibers/doi:10.1039%2Fc9cp01891c/rivista:PCCP. Physical chemistry chemical physics (Print)/anno:2019/pagina_da:10357/pagina_a:10369/intervallo_pagine:10357–10369/volume:21

A new type of polymer blend, prepared by electrospinning nanofibers containing the immiscible polymers polyvinylidene fluoride (PVDF, 10 wt%) and Nafion® perfluorosulfonic acid (90 wt%), has been characterized experimentally. The internal nanofiber

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4b6214b012ef25950e0b7eae1c64b8cc

High molecular weight polyketones by CO-ethene copolymerization catalysed with Pd(II)-phosphine complexes in homogeneous phase in formic acid

Autor: Luigi Toniolo, Gianni Cavinato

Publikováno v: Inorganic Chemistry Communications. 123:108358

[PdX2(PPh3)2]/PPh3 (X = HCOO, AcO, NO3, Cl, TsO; X2 = SO4) and [Pd(AcO)2(dppf)] in HCOOH with 5% H2O catalyse the CO-ethene copolymerization to high molecular weight polyketones (2700–2900 gPK (gPd⋅h)−1 at 333 K, 4.5 MPa of CO/ethene 1/1; M ¯

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::17b597d20e5f800a1afe1f681050ff5f
https://doi.org/10.1016/j.inoche.2020.108358

Properties of anion exchange membrane based on polyamine: Effect of functionalized silica particles prepared by sol-gel method

Autor: Elisa Cappelletto, Keti Vezzù, Narges Ataollahi, Rosa Di Maggio, Emanuela Callone, Sandra Dirè, Gianni Cavinato, Vito Di Noto, Paolo Scardi

Publikováno v: Solid state ionics
322 (2018): 85–92. doi:10.1016/j.ssi.2018.04.022
info:cnr-pdr/source/autori:Ataollahi N.; Cappelletto E.; Vezzu K.; Di Noto V.; Cavinato G.; Callone E.; Dire S.; Scardi P.; Di Maggio R./titolo:Properties of anion exchange membrane based on polyamine: Effect of functionalized silica particles prepared by sol-gel method/doi:10.1016%2Fj.ssi.2018.04.022/rivista:Solid state ionics (Print)/anno:2018/pagina_da:85/pagina_a:92/intervallo_pagine:85–92/volume:322

Membranes of polyamine (PA-SiNH 2 ) m , containing silica reacted with 3-aminopropyltriethoxysilane (APTES) in hydrolytic conditions were prepared via solution casting, followed by methylation and ion exchange process. The influence of amino-function

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::601c3aa94cf9f0e1f71547f3b639a93d
https://publications.cnr.it/doc/389629

A Polyketone-based Anion Exchange Membrane for Electrochemical Applications: Synthesis and Characterization

Autor: Graeme Nawn, F. Girardi, Gianni Cavinato, Rosa Di Maggio, Paolo Scardi, Vito Di Noto, Giuseppe Pace, Narges Ataollahi, Keti Vezzù

Publikováno v: Electrochimica acta 226 (2017): 148–157. doi:10.1016/j.electacta.2016.12.150
info:cnr-pdr/source/autori:Ataollahi N.; Vezzu K.; Nawn G.; Pace G.; Cavinato G.; Girardi F.; Scardi P.; Di Noto V.; Di Maggio R./titolo:A Polyketone-based Anion Exchange Membrane for Electrochemical Applications: Synthesis and Characterization/doi:10.1016%2Fj.electacta.2016.12.150/rivista:Electrochimica acta/anno:2017/pagina_da:148/pagina_a:157/intervallo_pagine:148–157/volume:226

An anion exchange membrane (AEM) was made with a modified polyketone (PK). AEMs of polyamines were prepared in a three-step procedure: (I) PK synthesis using ethylene and carbon monoxide, supported by a Pd catalyst, followed by the introduction of 1,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b4e2d562a602bef1a53dea5c60ac15d1
http://hdl.handle.net/11577/3226718