Zobrazeno 1 - 10
of 273
pro vyhledávání: '"G.Ye. Zaikov"'
Publikováno v:
Polymer Science U.S.S.R.. 33:247-252
Change in the mean viscous MM of polystyrene when processed on a disc extruder in a mixture with PE of varied composition has been studied. The results are analysed with reference to the rheological properties of PE-PS blends and the character of the
Publikováno v:
Polymer Science U.S.S.R.. 33:843-861
Oriented PE and PP samples have been studied on exposure to mechanical, temperature and oxidative factors. The complex nature of the change in molecular mobility on static loading of oriented polyolefins has been established. Deformation, degree of s
Autor:
G.Ye. Zaikov, A. L. Iordanskii, A.V. Trezvova, O.G. Fortunatov, Ye.V. Zolotova, L.P. Razumovskii
Publikováno v:
Polymer Science U.S.S.R.. 33:902-909
The authors have investigated the influence of the rigid block fraction, the conditions of synthesis and the modes of formation of films of segmented Gemotan-T polyether urethane on the structural and sorption-diffusion properties. From the results o
Publikováno v:
Polymer Science U.S.S.R.. 23:1666-1674
A study has been made of the influence of external loads on the rate of ozone oxidation of oriented high- and low-density polyethylene specimens, under regimes of constant stress and strain. It is shown that tensile stress has an accelerating effect
Publikováno v:
Polymer Science U.S.S.R.. 30:177-182
The variation of mechanical, structural and dynamic parameters and MD of oriented PP were examined during ozone oxidation. It is assumed that the improvement of mechanical properties at the initial stage of oxidation is due to the crystallization of
Publikováno v:
Polymer Science U.S.S.R.. 21:1843-1846
Using isotope H → D exchange coefficients of adsorption bands of ND groups were determined at 2480 cm−1 and of crystalline NH groups at 3300 cm−1. Extinction coefficients obtained enable the crystallinity of polycaproamide films to be calculate
Publikováno v:
Polymer Science U.S.S.R.. 27:1948-1956
Some features of the sorption and dissolution of low molecular weight additive in a polymer are discussed on the basis of a model presenting the polymer as a solution of distortion of short-range order in a medium consisting of ideally ordered macrom
Publikováno v:
Polymer Science U.S.S.R.. 28:943-951
A trimolecular mechanism is postulated for the reaction of polypropylene with oxygen, which represents the first step initiating the kinetic chain of oxidation. Crosslinking of polypropylene observed experimentally in the initial stages of oxidation
Publikováno v:
Polymer Science U.S.S.R.. 29:2149-2155
The diffusion of water in non-isocyanate polyurethane acetals of various nature and composition is studied, and a direct relation between the polymer composition, crystallinity, morphology, and diffusional characteristics is found. It is shown that t
Autor:
G.Ye. Zaikov, P.P. Nechayev
Publikováno v:
Polymer Science U.S.S.R.. 27:1101-1111
The kinetic mechanisms of acid-base hydrolysis of amides, esters, imides and other compounds are discussed from the viewpoint of the problem of regenerating monomers from heterochain polymers.