Zobrazeno 1 - 10
of 108
pro vyhledávání: '"G.P. McQuillan"'
Publikováno v:
J. Chem. Soc., Dalton Trans.. :3963-3974
Vibrational spectra have been obtained for the CH3CH2, CH3CD2, CD3CH2, CHD2CD2 and (for Fe and Mo) CHD2CHD isotopomers of [MEt(cp)(CO)2](M = Fe or Ru) and [MEt(cp)(CO)3](M = Mo or W)(cp =η5-C5H5). The isolated CH stretching frequencies νis(CH), obs
Publikováno v:
J. Chem. Soc., Dalton Trans.. :3955-3961
Vibrational spectra have been recorded for the CH3, CD3 and CHD2 isotopomers of [MMe(cp)(CO)2](M = Fe or Ru; cp = cyclopentadienyl). The effects of Fermi resonance were considered in detail and the resonance-corrected CH and CD stretching frequencies
Publikováno v:
Crystals; Volume 1; Issue 2; Pages: 47-58
Crystals, Vol 1, Iss 2, Pp 47-58 (2011)
Crystals, Vol 1, Iss 2, Pp 47-58 (2011)
The syntheses and single-crystal structures of Mo(CO)3(phen)(dipy) (1), Mo(CO)3(biquin)(dipy) (2) and Mo(CO)3(dpme)(dipy) (3), (phen = 1,10-phenanthroline, C12H8N2; dipy = 2,2'-dipyridylamine, C10H9N3; biquin = 2,2'-biquinoline, C18H12N2; dpme = 2,2'
Publikováno v:
Journal of Molecular Structure. 247:73-87
Infrared spectra have been recorded between 4000 and 200 cm −1 from 12 CH 3 TiCl 3 in the gas and solid, and 12 CD 3 TiCl 3 in the gas phase. 13 CH 3 TiCl 3 and CHD 2 TiCl 3 have been studied in the gas phase down to 450 cm − . All fundamentals,
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 57:m181-m182
The title compound, [TiCl2(C16H22)], (I), is isomorphous with the corresponding and previously described Zr compound [(II); Kimura et al. (1998), Chem. Lett. pp. 571–572] and, apart from the difference in space group used in the structure refinemen
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 63:m2918-m2918
The previous structure report [Howie & McQuillan (1986). J. Chem. Soc. Dalton Trans. pp. 759–764] of the title compound, [Mo(C10H8N2)(C10H9N3)(CO)3], has been corrected. In the present structure, the precision of the Mo—C and Mo—N bond distance
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 63:m2491-m2491
In the title compound, [Mo(CO)2(phen)2] (phen = C12H8N2), the Mo atom adopts a cis-MoC2N4 geometry. The C—Mo—C angle of 88.0 (3)° is close to its ideal, undistorted value and the dihedral angle between the phen mean planes is 84.79 (9)°. A C—
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 63:m2493-m2493
In the title compound, [Mo(CO)3(C18H15P)(C10H8N2)] or C31H23MoN2O3P, the carbonyl groups are attached to one face of the MoC3N2P octahedron. In the crystal structure, a short C—H⋯O interaction (H⋯O = 2.41 A) may help to establish the packin
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 63:m2452-m2452
In the title compound, [Mo(C18H12N2)(CO)4], the differences in the Mo—C and C—O bond lengths may be interpreted in terms of a classical back-bonding model of electronic structure. In the crystal structure, an acute C—H⋯O interaction may h
Autor:
G.P. McQuillan, Ian A. Oxton
Publikováno v:
Journal of Molecular Structure. 64:173-181
Vibrational data are reported for complexes of tetraethyl-,tetrapropyl-and tetrabutyl-1,2-dithioxodi-λ 5 -phosphanes (tetraalkyldiphosphine disulphides) P 2 R 4 S 2 with zinc, cadmium, mercury and cobalt halides. The P—P stretching frequencies in