Zobrazeno 1 - 10
of 109
pro vyhledávání: '"G.M. Tseitlin"'
Publikováno v:
Polymer Science U.S.S.R.. 32:327-334
The main laws governing the thermal transformations in vacuum of phenylquinoxalines, which are compounds which simulate the elementary units of polyphenylquinoxalines are studied. These reactions involve a radical-chain mechanism. The initiation stag
Publikováno v:
Polymer Science U.S.S.R.. 31:321-327
The main patterns of the thermal degradation of polyphenylquinoxalinesin vacuo have been studied. It is shown that the thermal conversions of these substances follow the radical chain mechanism in two stages. First is crosslinking of the macromolecul
Publikováno v:
Polymer Science U.S.S.R.. 26:1909-1916
A study has been made of the disproportionation of low molecular weight products of hydrolytic polycondensation of tetraethoxysilane, viz hexaethoxydisiloxane and octaethoxysilane, in the presence of nucleophilic agents (KF, Me 4 NF, Me 4 NOH, Me 3 S
Publikováno v:
Polymer Science U.S.S.R.. 27:385-392
The processes taking place in the course of hydrolytic polycondensation of tetraethoxysilane (TES) at the molar ratio n = [H2O]0:[TES]0 = 0·2–1·5, were studied by means of the changes of the content of linear and cyclic ethoxysiloxanes. It was fo
Autor:
B.N. Feofanov, S.-S.A. Pavlova, S. A. Siling, V.V. Korshak, G.M. Tseitlin, S.V. Vinogradova, Inga A. Ronova
Publikováno v:
Polymer Science U.S.S.R.. 29:1694-1700
Polyisoindoxazenes based on diaminophenylanthracene are synthesized and their properties are studied. The values of the Kuhn segments for the polymers obtained are calculated by the Monte-Carlo method. It is established that a polymer based on pyrome
Autor:
Z. Sh. Dzhaparidze, Alexander L. Rusanov, I. M. Gverdtsiteli, G.M. Tseitlin, V.V. Korshak, A.Ya. Chernikhov, D. S. Tugushi
Publikováno v:
Polymer Science U.S.S.R.. 21:2051-2056
A new method was developed for the synthesis of polybenzoxazoles, which is based on the interaction of dicarboxylic acid dichlorides with bis-[(o-nitro)phenols], the reduction of o-nitrosubstituents of poly[(o-nitro)esters] obtained and the simultane
Autor:
G.M. Tseitlin, V.V. Korshak, N.S. Zabel'nikov, V.G. Danilov, Yu.Ye. Doroshenko, V.A. Khomutov
Publikováno v:
Polymer Science U.S.S.R.. 16:3111-3121
An investigation was carried out of the heat-resistances of aromatic polybenzoxazoles containing bulky polar groups, such as phthalide and N-phenylphthalimidine, in the main chain, and of a number of model compounds. The chemical composition of the p
Publikováno v:
Polymer Science U.S.S.R.. 30:731-739
The influence of the chain length of poly(ethylene oxides) on the reactivity of their terminal aromatic acid chloride groups in acceptor-catalytic esterification has been determined by kinetic investigations in dilute solutions. It is established tha
Publikováno v:
Polymer Science U.S.S.R.. 20:971-978
A kinetic study has been made of CO and CO 2 evolution during the degradation of benzanilide and N-methylbenzanilide under vacuum in the presence of water. In addition the degradation of benzanilide in the presence of benzoic acid and aniline has bee
Autor:
A.Ya. Chernikhov, N.V. Karyakin, Alexander L. Rusanov, V.V. Korshak, G.M. Tseitlin, G.V. Kazakova
Publikováno v:
Polymer Science U.S.S.R.. 28:1569-1573
The authors have determined the enthalpies of the reactions of polycondensation of 3,3′-dihydroxy-4,4′-diaminodiphenylmethane (DHDA) with the diacid chlorides of iso- and terephthalic acids in different solvents. Energetics of the interaction of