Zobrazeno 1 - 10
of 119
pro vyhledávání: '"G.I. Panov"'
Publikováno v:
Applied Catalysis A: General. :10-16
Gas phase oxidation of phenol by nitrous oxide for preparation of dihydroxybenzenes (DHB) is of significant interest. However, due to experimental difficulties caused by the high boiling points of DHB (240–285 °C), no detailed investigation of thi
Publikováno v:
Applied Catalysis B: Environmental. 91:174-179
The kinetics and the mechanism of nitrous oxide decomposition (NOD) were studied using a set of FeZSM-5 samples with a wide variation in concentration of α-sites, which are special complexes of bivalent iron (FeII)α stabilized in the micropore spac
Autor:
G.I. Panov
Publikováno v:
Reaction Kinetics and Catalysis Letters. 84:383-388
Nitrous oxide is known to provide non-catalytic liquid phase oxidation of alkenes to carbonyl compounds (the carboxidation reaction). This paper shows that carboxidation of cyclohexene can be successfully conducted in the gas phase, too. The gas phas
Publikováno v:
Applied Catalysis A: General. 249:327-343
Benzene to phenol oxidation by nitrous oxide over the Fe-ZSM-5 catalyst was studied at 648–698 K and near atmospheric pressure using a bench scale plug flow reactor with a feed gas concentration of 30–80 mol% benzene, 1.5–5.0 mol% N 2 O, and 0
Publikováno v:
Applied Catalysis A: General. 241:113-121
The object of the study was to determine the effect of coke, formed in the nitrous oxide oxidation of benzene-to-phenol (BTOP), on the catalytic and texture properties of ZSM-5. The study was conducted on three series of catalyst samples. The samples
Publikováno v:
Topics in Catalysis. 23:137-143
According to previous Mossbauer data [1] α-sites formation at the activation of Fe-containing zeolites is accompanied by irreversible “self-reduction” of the iron, proceeding without participation of an external reducing agent. Reduced Fe2+ ions
Publikováno v:
Applied Catalysis A: General. 227:143-157
Catalytic properties of Fe introduced in the pentasil type zeolite matrices of various composition (B-ZSM-5, Al-ZSM-5, Ga-ZSM-5, Ti-ZSM-5) have been studied. All the matrices were shown to be inert in the title reaction. However, upon iron introducti
Autor:
G.I. Panov
Publikováno v:
CATTECH. 4:18-31
Recent decades show impressive progress in oxidation catalysis, resulting in many novel industrial technologies. However, there is a difficult and challenging field, that of oxidation reactions which cannot be selectively implemented via traditional
Autor:
A.S. Kharitonov, Konstantin A. Dubkov, L.V. Pirutko, Vladimir I. Sobolev, E. A. Paukshtis, Mikhail A. Rodkin, G.I. Panov
Publikováno v:
Applied Catalysis A: General. 141:185-192
Oxidation of benzene to phenol with nitrous oxide being an untypical reaction for zeolite catalysis arouses a great interest among researchers. Several hypotheses concerning reaction mechanism are discussed. Some of them assume a key role of the Bron
Publikováno v:
Scopus-Elsevier
Evolution of ZSM-11 zeolite crystal and pore structure has been studied at 150°C depending on the synthesis time. The amorphous gel was shown to be catalytically inert over the whole induction period, which precedes the crystallization process. The