Zobrazeno 1 - 10
of 39
pro vyhledávání: '"G.D. Lei"'
Publikováno v:
Applied Catalysis A: General. 146:165-180
Skeletal isomerizations of n-pentane and n-butane have been studied at 11 bar in a microflow reactor over platinum containing sulfated zirconia (PtSZ) catalysts. The isomerization rate of n-pentane is about seven times higher than that of n-butane; s
Publikováno v:
Applied Catalysis A: General. 142:347-359
When small molecules inside one-dimensional micropores of zeolites are unable to pass along each other, transport is limited by single file diffusion . Product molecules generated inside such micropores are unable to escape to the gas phase if the po
Publikováno v:
Journal of Catalysis. 161:43-54
The dependence of the deactivation rate of Cu/ZSM-5 lean NOxreduction catalysts on the composition of the feed was studied. No catalyst deactivation was observed in the absence of H2O at 400°C after 160 h. Catalyst deactivation was much faster if th
Publikováno v:
Journal of Catalysis. 159:90-98
The conversion of methylcyclopentane (MCP) has been studied overzeolite Y supported rhodium catalysts with a variety of protonconcentrations. Ring opening (RO) of MCP to hexane isomers iscatalyzed by metal sites, but ring enlargement (RE) of MCP tocy
Publikováno v:
Applied Catalysis A: General. 137:167-177
Isomerization of small alkanes is compared over two bifunctional catalysts with similar concentrations of metal and acid sites and similar strenths of Bronsted acid sites. The catalytic performance and the kinetic parameters are significantly differe
Publikováno v:
Journal of Catalysis. 158:327-335
The nature of adsorbed nitrogen oxide complexes (NO y ) has been identified by FTIR spectroscopy. Nitrito groups are most prominent on Co/ZSM-5. These complexes are stable at 150°C in He but are reduced upon exposure to either C 3 H 8 or CH 4 leadin
Publikováno v:
Microporous Materials. 5:263-278
Exchange of [Rh(NH3)5(H2O)]3+ ions from aqueous solution into NaY starts at the surface of the zeolite grains; ion penetration into subsurface cavities is slow. A marked rhodium concentration profile from the surface to the interior of the granuli va
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 100:35-48
The isomerization of n-butane to i-butane has been studied at 11 bar in a microflow reactor over sulfated zirconia (SZ) and platinum containing sulfated zirconia (Pt-SZ) catalysts. In the presence of H2 a significantly higher temperature is required
Publikováno v:
Journal of Catalysis. 154:245-252
Unpromoted and manganese-promoted zeolite Y supported rhodium catalysts were tested for CO hydrogenation at 1 MPa and 250°C. The conditions of catalyst preparation by ion exchange, programmed calcination, programmed reduction and neutralization of a
Autor:
K. Fogash, James A. Dumesic, H. Trevino, Wolfgang M.H. Sachtler, V. Schunemann, G.D. Lei, D.C. Tomczak
Publikováno v:
Journal of Catalysis. 153:144-157
Mossbauer spectroscopy, temperature programmed reduction (TPR), and FTIR of adsorbed CO show that ion exchange of [Rh(NH3)4Cl]Cl2 and FeSO4 into NaY, followed by calcination and reduction in H2 up to 500°C, leads to Fe2+ ions and bimetallic RhFe clu