Influence of pressure (100 Pa–100 Mpa) on the pyrolysis of an alkane at moderate temperature (603 K–723 K): Experiments and kinetic modeling

Autor: Raymond Michels, F. Lannuzel, G. Scacchi, Roda Bounaceur, V. Burklé-Vitzthum, Paul-Marie Marquaire

Publikováno v: Journal of Analytical and Applied Pyrolysis
Journal of Analytical and Applied Pyrolysis, Elsevier, 2016, 122, pp.442-451. ⟨10.1016/j.jaap.2016.10.022⟩

Confined pyrolysis of n- octane was performed in a closed, constant-pressure gold reactor at pressure ranging 1 MPa–70 MPa, temperature between 603 K and 723 K and residence times from 1 h to 1 month. The main products of reaction are n- alkanes of

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::945cc9a4222ae16050a417b04a7049ed
https://doi.org/10.1016/j.jaap.2016.10.022

Modeling the Oxidation of Mixtures of Primary Reference Automobile Fuels

Autor: M. Cathonnet, F. Battin-Leclerc, Pierre-Alexandre Glaude, Philippe Dagaut, G. Scacchi, R. Fournet, G. M. Come, V. Conraud

Publikováno v: Energy & Fuels. 16:1186-1195

A kinetic model for the oxidation of mixtures of n-heptane/iso-octane, the primary reference fuels for octane rating in spark-ignited internal combustion engines, has been written by using the system of automatic generation of mechanisms developed in

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8bca2f1ec3f310d9706a8ccca31cdb1f
https://doi.org/10.1021/ef020025e

Chemical lumping of mechanisms generated by computer. Application to the modelling of normal butane oxidation

Autor: Eliseo Ranzi, Tiziano Faravelli, Pierre-Alexandre Glaude, Valérie Warth, Frédérique Battin-Leclerc, Roda Bounaceur, G Scacchi, GM Côme

Publikováno v: Scopus-Elsevier
Journal de Chimie Physique
Journal de Chimie Physique, 1996, pp.1472-1491. ⟨10.1051/jcp/1996931472⟩

This paper describes a technique which permits to drastically reduce comprehensive primary mechanisms which can be obtained by computer aided design in the case of the gas-phase oxidation of alkanes. This procedure has been tested by reducing a prima

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e0cb795813fdd68b4255d2aaf081514c
https://doi.org/10.1051/jcp/1996931472

Kinetics and modeling of the thermal reaction of propene at 800 K. Part II. Propene in the presence of hydrogen

Autor: D. Perrin, R. Martin, P. Barbé, G. Scacchi

Publikováno v: International Journal of Chemical Kinetics. 28:849-863

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::fdbcb694737c1348dd45943fc83fc788
https://doi.org/10.1002/(sici)1097-4601(1996)28:11<849::aid-kin6>3.0.co

The dual nature of carbon: Catalyst and inhibitor

Autor: G. Scacchi, Rashmi Venkateswaran, M.H. Back

Publikováno v: Carbon. 32:911-919

The nature of carbon in the form of thin films as an inhibitor and as a catalyst was studied using the conversion of methane as a test reaction. The carbon films were formed by pyrolysis of either propylene (C p ) or methane (C m ) in a quartz reacto

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::611c505735df05b1f40af57b90908a64
https://doi.org/10.1016/0008-6223(94)90048-5