Zobrazeno 1 - 9
of 9
pro vyhledávání: '"G. M. Zachinyaev"'
Publikováno v:
Radiochemistry. 61:671-675
Thermal stability of hydrazine nitrate (HN) in solutions in 4–12 M HNO3 in the temperature interval 70–150°C was studied. Exothermic reactions accompanied by gas evolution arise in such systems under definite conditions. The intensity of such re
Publikováno v:
Radiochemistry. 61:665-670
The thermal stability of mixtures of TBP and its solutions in diluents with uranyl nitrate (UN) at 150–200°C was evaluated. Exothermic self-accelerating oxidation processes (thermal explosions) arise in mixtures with TBP at 160–170°C. In mixtur
Publikováno v:
Radiochemistry. 59:512-519
Causes of initiation of exothermic self-accelerating oxidation processes in mixtures of TBP with HNO3 are analyzed. The main condition is heating of the mixtures to temperatures (Т st) above which the heat release in the chemical reaction starts to
Autor:
E. R. Nazin, A. V. Rodin, G. M. Zachinyaev, Boris F. Myasoedov, G. P. Thorzhnitsky, Elena Belova
Publikováno v:
Nuclear Technology. 194:369-378
The influence of thermal and gamma radiation effects on the characteristics of the thermal explosion of mixtures of tributyl phosphate (TBP) and nitric acid was studied. The products of sequential ...
Publikováno v:
Radiochemistry. 46:54-57
Thermochemical degradation of two-phase systems TBP-HNO3 and 30% TBP in dodecane-HNO3 (HNO3 concentration 1.5-10 M) on heating in a sealed vessel to 130-170°C is studied. Heating to 130-150°C promotes exothermic oxidation of the organic phase, resu
Autor:
S. A. Bartenev, V. N. Romanovskii, S. A. Strelkov, G. F. Egorov, M. L. Hyder, L. N. Lazarev, E. R. Nazin, N. G. Firsin, G. M. Zachinyaev
Publikováno v:
Radiochemistry. 45:51-55
Thermal degradation of VP-1AP anion exchanger and its mixtures with HNO3 was studied in open vessels at 40 to 260°C. The anion exchanger ignites only after drying and heating to 220-260°C. Heating VP-1AP mixtures with 3-12 M HNO3 to 100°C is accom
Autor:
V. N. Romanovskii, E. R. Nazin, S. A. Bartenev, G. M. Zachinyaev, S. A. Strelkov, M. L. Hyder, G. F. Egorov, V. M. Kalashnikov, L. N. Lazarev, N. G. Firsin
Publikováno v:
Radiochemistry. 44:157-161
Variation of physicochemical characteristics of VP-1AP anion-exchange resin in HNO3 solutions on heating and under the action of external γ-radiation up to the absorbed dose of 5 MGy was studied. It was shown that at thermal treatment of anion excha
Autor:
S. A. Bartenev, M. L. Hyder, G. M. Zachinyaev, L. N. Lazarev, S. A. Strelkov, L. V. Krasnikov, E. R. Nazin, N. G. Firsin, G. F. Egorov, V. N. Romanovskii
Publikováno v:
Radiochemistry. 44:162-166
Thermal gravimetric analysis of the samples of VP-1AP anion exchanger in sulfate and nitrate forms was carried out. In the derivatograms of the anion exchanger in the nitrate form there are one endothermic and two exothermic peaks (∼100, 160-180, a
Autor:
S. A. Bartenev, V. N. Romanovskii, L. N. Lazarev, G. M. Zachinyaev, S. A. Strelkov, E. R. Nazin
Publikováno v:
Radiochemistry. 43:289-292
Gas liberation in systems ion exchanger-nitric acid solution in open and closed vessels under the action of elevated temperature and ionizing radiation is studied. Preliminary data on the detonation properties of VP-1AP anion-exchange resin are given