Zobrazeno 1 - 10
of 21
pro vyhledávání: '"G. J. Lamprecht"'
Publikováno v:
Inorganic Chemistry. 36:2982-2987
The chalcogenide-rich trinuclear Mo(IV)(3) clusters [Mo(3)Y(7)(H(2)O)(6)](4+), containing single m(3)-(Y(2)(-)) and three m-(Y(2)(2)(-)) core ligands, have been obtained for the first time from polymeric {Mo(3)Y(7)Br(4)}(x)() via [Mo(3)Y(7)Br(6)](2)(
Publikováno v:
Inorganic Chemistry. 35:5531-5535
The kinetics of conversion of an edge-linked double cube, in this case [{Mo(3)PdS(4)(H(2)O)(9)}(2)](8+), to the corresponding single cube [Mo(3)(PdX)S(4)(H(2)O)(9)](4+), has been studied for the first time. Reaction is induced by six reagents X = CO,
Autor:
A. G. Sykes, C. A. Routledge, Chee-Hun Kwak, G. J. Lamprecht, David M. Saysell, M.-C. Hong, C. D. Borman, Vladimir P. Fedin
Publikováno v:
Pure and Applied Chemistry. 67:305-310
Studies on Mo-S cluster complexes including cuboidal (MO~S~H~O)~~I"+ (n = 4,5,6) and heterometallic (Mo3MS4(H20),14+ (x = 10,121 complexes are described. Such cubes are stable in aqueous solution, and provide a ready means of studying redox and subst
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 49:760-763
[Rh(C 14 H 13 FeO 2 )(C 8 H 12 )], M r =480.2, triclinic, P1, a=11.658 (1), b=13.001 (1), c=15.251 (2) A, α=70.621 (8), β=68.538 (8), γ=66.049 (7) o , V=1919.8 (3) A 3 , Z=4, D m =1.63, D x =1.66 g cm -3 , λ(Mo Kα)=0.71073 A, μ=16.15 cm -1 , T=
Publikováno v:
ChemInform. 28
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 54:1085-1087
The bicyclic phosphite 4-methyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane reacts in a 1:1 molar ratio with dicarbonyl(1,3-diphenyl-1,3-propanedionato-O,O')-rhodium(I) to yield the title compound, [Rh(C 15 H 11 O 2 )(C 5 H 9 O 3 P)(CO)], with square-
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 53:1403-1405
One carbonyl group in dicarbonyl(1,3-diphenyl-1,3-propanedionato-O,O')rhodium(I) was substituted by triphenylphosphine to yield the title compound, [Rh(C 15 H 11 O 2 )(C 18 H 15 P)(CO)], which has a square-planar geometry about the Rh atom. There are
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 52:3000-3002
The title compound, μ-[(E)-1,3-di-η 5 -cyclopentadienyl-2-buten-1-one]bis(η 5 -cyclopentadienyliron)-water (4/1), [Fe 2 (C 5 H 5 ) 2 (C 14 H 12 O)].0.25H 2 O, has two independent [Fe 2 (C 5 H 5 ) 2 (C 14 H 12 O)] molecules in the asymmetric unit.
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 51:1748-1750
The structure determination of the title complex, [Ir(C 5 H 7 OS)(CH 3 )(I)(C 8 H 12 )], revealed that the oxidative addition of iodomethane to (η 4 -1,5-cyclooctadiene)-(thioacetylacetonato)iridium(I) results in the formation of the trans isomer. T
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 49:82-84
[Rh(C 14 H 10 F 3 FeO 2 )(CO){P(C 6 H 5 ) 3 }], M r =716.28, triclinic, P1, a=10.439 (2), b=12.605 (1), c=13.307 (1) A, α=107.77 (1), β=100.45 (1), γ=107.76 (1) o , V=1513.5 (4) A 3 , Z=2, D m =1.57, D x =1.52 g cm -3 , λ(Mo Kα)=0.71073 A, μ=11