Zobrazeno 1 - 2
of 2
pro vyhledávání: '"G T, Dunning"'
Publikováno v:
Physical chemistry chemical physics : PCCP. 17(14)
Time-resolved infra-red (IR) absorption spectroscopy is used to follow the production of HF from the reaction of fluorine atoms in liquid acetonitrile (CH3CN). Photolysis of dissolved XeF2 using ∼50 fs duration, 267 nm laser pulses generates F atom
Autor:
G T, Dunning, D R, Glowacki, T J, Preston, S J, Greaves, G M, Greetham, I P, Clark, M, Towrie, J N, Harvey, A J, Orr-Ewing
Publikováno v:
Science (New York, N.Y.). 347(6221)
Solvent-solute interactions influence the mechanisms of chemical reactions in solution, but the response of the solvent is often slower than the reactive event. Here, we report that exothermic reactions of fluorine (F) atoms in d3-acetonitrile and d2