Modulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework

Autor: Zhenzhong Lu, Harry G. W. Godfrey, Ivan da Silva, Yongqiang Cheng, Mathew Savage, Floriana Tuna, Eric J. L. McInnes, Simon J. Teat, Kevin J. Gagnon, Mark D. Frogley, Pascal Manuel, Svemir Rudić, Anibal J. Ramirez-Cuesta, Timothy L. Easun, Sihai Yang, Martin Schröder

Publikováno v: Nature Communications, Vol 8, Iss 1, Pp 1-10 (2017)

Gaining molecular-level insight into host–guest binding interactions is fundamentally important, but experimentally challenging. Here, Schröder and co-workers study CO2–host hydrogen bonding interactions in a pair of isostructural redox-active V

Externí odkaz: https://doaj.org/article/d102796e45484256907a08dab1dbe753

Long-Term Stability of MFM-300(Al) toward Toxic Air Pollutants

Autor: Jonathan Potter, Harry G. W. Godfrey, Sihai Yang, Christopher G. Morris, Sarah J. Day, Chiu C. Tang, Martin Schröder, Stephen P. Thompson, Joseph H. Carter

Publikováno v: ACS Applied Materials & Interfaces
ACS Applied Materials Interface
Carter, J, Morris, C, Godfrey, H G W, Day, S J, Potter, J, Thompson, S P, Tang, C, Yang, S & Schröder, M 2020, ' Long-Term Stability of MFM-300(Al) Towards Toxic Air Pollutants ', ACS applied materials & interfaces . https://doi.org/10.1021/acsami.0c11134

Temperature- or pressure-swing sorption in porous metal–organic framework (MOF) materials has been proposed for new gas separation technologies. The high tunability of MOFs toward particular adsorbates and the relatively low energy penalty for syst

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::adfc33e23ccfa8bf56cdeb5599f67cfa
http://europepmc.org/articles/PMC7517712

Locating the binding domains in a highly selective mixed matrix membrane via synchrotron IR microspectroscopy

Autor: Gianfelice Cinque, Sihai Yang, Mathew Savage, Peter Rought, Harry G. W. Godfrey, Mark D. Frogley, Nicholas M. Jacques, Detlev Fritsch, Tamoghna Mitra, Martin Schröder, Lei Li

Publikováno v: Jacques, N M, Rought, P R E, Fritsch, D, Savage, M, Godfrey, H G W, Li, L, Mitra, T, Frogley, M D, Cinque, G, Yang, S & Schroder, M 2018, ' Locating the Binding Domains in a Highly Selective Mixed Matrix Membrane via Synchrotron IR Microspectroscopy ', Chemical Communications . https://doi.org/10.1039/C7CC08932E
Chemical Communications

The binding domains within a mixed matrix membrane (MMM) that is selective for CO2 comprising MFM-300(Al) and the polymer 6FDA-Durene-DABA have been established via in situ synchrotron IR microspectroscopy. The MOF crystals are fully accessible and p

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2ecd0b87abe973b7fb2be362f480ab55
https://doi.org/10.1039/c7cc08932e

Analysis by synchrotron X-ray scattering of the kinetics of formation of an Fe-based metal-organic framework with high CO 2 adsorption

Autor: Sihai Yang, Oxana V. Magdysyuk, Lydia Briggs, William J. F. Trenholme, Mark D. Frogley, Claire A. Murray, Michael Drakopoulos, Harry G. W. Godfrey, Xue Han, Mathew Savage, Chiu C. Tang, Christopher G. Morris, Martin Schröder, Gianfelice Cinque, Louis Kimberley

Publikováno v: APL Materials
Godfrey, H, Briggs, L, Han, X, Trenholme, W, Morris, C, Savage, M, Kimberley, L, Magdysyuk, O, Drakopoulous, M, Murray, C A, Tang, C C, Frogley, M D, Cinque, G, Yang, S & Schroder, M 2019, ' Analysis by synchrotron X-ray scattering of the kinetics of formation of an Fe-based metal-organic framework with high CO2 adsorption ', APL Materials, vol. 7, no. 11 . https://doi.org/10.1063/1.5121644
APL Materials, Vol 7, Iss 11, Pp 111104-111104-8 (2019)

Understanding the mechanism of assembly and function of metal-organic frameworks (MOFs) is important for the development of practical materials. Herein we report a time-resolved diffraction analysis of the kinetics of formation of a robust MOF, MFM-3

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::181e9bb255668a461d7b04787aafd85b

Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Framework

Autor: Harry G W, Godfrey, Ivan, da Silva, Lydia, Briggs, Joseph H, Carter, Christopher G, Morris, Mathew, Savage, Timothy L, Easun, Pascal, Manuel, Claire A, Murray, Chiu C, Tang, Mark D, Frogley, Gianfelice, Cinque, Sihai, Yang, Martin, Schröder

Publikováno v: Angewandte Chemie (International Ed. in English)

MFM‐300(Al) shows reversible uptake of NH3 (15.7 mmol g−1 at 273 K and 1.0 bar) over 50 cycles with an exceptional packing density of 0.62 g cm−3 at 293 K. In situ neutron powder diffraction and synchrotron FTIR micro‐spectroscopy on ND3@MFM�

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::e90abb8fa1e4eaa35d6584d5827fd085
https://pubmed.ncbi.nlm.nih.gov/30098090