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Akademický článek

Capture the missing: formation of (PbBi3)− and {[AuPb5Bi3]2}4− via atom exchange or reorganization of the pseudo‐tetrahedral Zintl anion (Pb2Bi2)2−

Autor: Fuxing Pan, Lukas Guggolz, Stefanie Dehnen

Publikováno v: Natural Sciences, Vol 2, Iss 3, Pp n/a-n/a (2022)

Abstract (Pseudo‐)tetrahedral p‐block atom units have been attracting the interest of many scientists, mainly regarding their use as elegant starting materials for compounds with larger molecular or extended architectures. The isoelectronic four�

Externí odkaz: https://doaj.org/article/bbbabb339ee048a5915dec56a111da8c

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Cluster Chemistry with ( Pseudo -)Tetrahedra Involving Group 13–15 (Semi-)Metal Atoms

Autor: Lukas Guggolz, Fuxing Pan, Stefanie Dehnen

Publikováno v: CCS Chemistry. 4:809-824

Compounds containing (pseudo-)tetrahedral main group (semi-)metal units are fundamentally important in three aspects. First, they provide new strategies for the stabilization of tetrahedral units, ...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::68768846125d27bb2d04d0289f46abf0
https://doi.org/10.31635/ccschem.021.202101340

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Bismuth-Based Metal Clusters─From Molecular Aesthetics to Contemporary Materials Science

Autor: Fuxing Pan, Benjamin Peerless, Stefanie Dehnen

Publikováno v: Accounts of Chemical Research, 56 (9), 1018–1030

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d7b16b1df10b5b57e6365beb92cbcf6b

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Tetrahedral [Sb(AuMe) 4 ] 3− Occurring in Multimetallic Cluster Syntheses: About the Structure‐Directing Role of Methyl Groups

Autor: Florian Weigend, Stefanie Dehnen, Marcel Lukanowski, Fuxing Pan

Publikováno v: Angewandte Chemie International Edition, 60 (47), 25042–25047

The anion of [K(crypt-222)]3 [Sb(AuMe)4 ]⋅py (1; crypt-222=4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane; py=pyridine) represents a rare example of a homoleptic heavy p-block metal atom being surrounded by four free-standing transition

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e322ea2ea049687cceed78e95bb8021c
https://doi.org/10.1002/ange.202110526

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Cover Picture: Between Elemental Match and Mismatch: From K 12 Ge 3.5 Sb 6 to Salts of (Ge 2 Sb 2 ) 2− , (Ge 4 Sb 12 ) 4− , and (Ge 4 Sb 14 ) 4− (Angew. Chem. Int. Ed. 41/2022)

Autor: Katrin Beuthert, Fuxing Pan, Lukas Guggolz, Robert J. Wilson, Jan Hempelmann, Richard Dronskowski, Stefanie Dehnen

Publikováno v: Angewandte Chemie International Edition. 61

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7dd0cecb478244a0689b5a926ee64f3d
https://doi.org/10.1002/anie.202212564

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Titelbild: Between Elemental Match and Mismatch: From K 12 Ge 3.5 Sb 6 to Salts of (Ge 2 Sb 2 ) 2− , (Ge 4 Sb 12 ) 4− , and (Ge 4 Sb 14 ) 4− (Angew. Chem. 41/2022)

Autor: Katrin Beuthert, Fuxing Pan, Lukas Guggolz, Robert J. Wilson, Jan Hempelmann, Richard Dronskowski, Stefanie Dehnen

Publikováno v: Angewandte Chemie. 134

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1ed17a6e57ec96eabf05342fa499b900
https://doi.org/10.1002/ange.202212564

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Between Elemental Match and Mismatch: From K 12 Ge 3.5 Sb 6 to Salts of (Ge 2 Sb 2 ) 2− , (Ge 4 Sb 12 ) 4− , and (Ge 4 Sb 14 ) 4−

Autor: Katrin Beuthert, Fuxing Pan, Lukas Guggolz, Robert J. Wilson, Jan Hempelmann, Richard Dronskowski, Stefanie Dehnen

Publikováno v: Angewandte Chemie International Edition. 61

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2b98165a50454fc6136c1e5cf6226eae
https://doi.org/10.1002/anie.202207232

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Insights into Formation and Relationship of Multimetallic Clusters: On the Way toward Bi-Rich Nanostructures

Autor: Stefanie Dehnen, Lukas Guggolz, Fuxing Pan, Shangxin Wei, Frank Tambornino, Armin Rainer Eulenstein

Publikováno v: Journal of the American Chemical Society. 143:7176-7188

Bismuth-rich polyanions show a unique potential in constructing nanostructured bismuth-based materials, but they are still poorly investigated. We use a ternary precursor of the nominal composition "K5Ga2Bi4" for the formation of [K(crypt-222)]+ salt

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6753d96bcf09c6414bfe82d98475a2d2
https://doi.org/10.1021/jacs.1c02653

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