Synthesis, structure, and electrochemical properties of N,Nʹ-bis(ferrocenylmethylene)ethylenediamine Schiff base and its metal complexes

Autor: Tugba Akcan Kardas, Yurdanur Akgül, Funda Demirhan, Hülya Avcı Özbek

The reaction of N,N'-bis(ferrocenylmethylene)ethylenediamine (FcNN) Schiff base with metal salts gave SnCl4FcNN (1), SnCl2FcNN(H2O)2 (2), Sn2(CH3)4Cl4FcNN (3), Ti2Cl8FcNN (4), CdFcNN(NO3)2 (5), and CuFcNN(NO3)2 (6). New complexes (1)–(6) were chara

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3872409a014712477cd602a615f599b7

1-Ferrocenylmethyl-3-(2,4,6-trimethylbenzyl)-1H-imidazolidin-3-ium iodide andtrans-bis(3-benzyl-1-ferrocenylmethyl-1H-imidazolidin-2-ylidene)diiodidopalladium(II)

Autor: Bekir Çetinkaya, Funda Demirhan, Jean-Claude Daran, Özgür Yıldırım

Publikováno v: Acta Crystallographica Section C: Crystal Structure Communications
Acta Crystallographica Section C: Crystal Structure Communications, International Union of Crystallography, 2012, 68 (2), pp.m48-m52. ⟨10.1107/S0108270112000601⟩

Owing to increasing interest in the use of N-heterocyclic carbenes (NHCs) based on imidazolidinium ions as ligands in the design of highly efficient transition-metal-based homogeneous catalysts, the characterizations of the 1-ferrocenylmethyl-3-(2,4,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::049ef1bd188c0456bc5a02d66f08da37
https://doi.org/10.1107/s0108270112000601

Aqueous Reduction of [Cp*2W2O5]: Characterization of the Triangular Clusters [Cp*3W3O4(OH)2]2+and [Cp*3W3O6]+– Comparison with Molybdenum

Autor: Rinaldo Poli, Pelin Sözen, Funda Demirhan, Chiara Dinoi, Gülnur Taban, Ovadia Lev, Jean-Claude Daran, Deniz Demir, Jenny Gun, Petr V. Prikhodchenko

Publikováno v: European Journal of Inorganic Chemistry. 2007:4306-4316

Zinc reduction of Cp*2W2O5 in an acidified water–methanol medium affords the green 3-electron trinuclear cluster [Cp*3W3O4(OH)2]2+, isolated and crystallographically characterized as the triflate salt, 1. Upon exposure to air, this complex is oxidi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::dda58a72a727d15d66a0f939c6dda2a2
https://doi.org/10.1002/ejic.200700419

Reduction of [Mo2O5] by mercaptopropionic acid in an aqueous medium. Isolation and characterization of a dinuclear oxo- and 3-sulfido-proprionato(2-)-bridged molybdenum(IV) compound

Autor: Ovadia Lev, Jean-Claude Daran, Jenny Gun, Petr V. Prikhodchenko, Chiara Dinoi, Rinaldo Poli, Funda Demirhan

Publikováno v: Journal of Organometallic Chemistry. 692:2599-2605

Reaction of Cp*2Mo2O5 with HSCH2CH2COOH in acidic (by CF3COOH) 50:50 MeOH-H2O solvent at room temperature yields compound Cp*2Mo2(μ-O)(μ-SCH2CH2CO2)2, a dinuclear diamagnetic MoIV compound with a two-leg-sharing bis(four-legged piano stool) structu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ba5379364e62e518323aa42777cefe2f
https://doi.org/10.1016/j.jorganchem.2007.02.046

Reduction of [Cp* 2 Mo 2 O 5 ] in Aqueous Medium: Structure and Properties of a Triangular Mixed Oxo‐Hydroxo‐Bridged Product, [Cp* 3 Mo 3 (μ‐O) 2 (μ‐OH) 4 ](X) 2 (X = CF 3 CO 2 or CF 3 SO 3 )

Autor: Rinaldo Poli, Jean-Claude Daran, Miguel Baya, Funda Demirhan, Bahar Çağatay, Deniz Demir

Publikováno v: European Journal of Inorganic Chemistry. 2006:757-764

The reduction of [Cp*2Mo2O5] with Zn in a MeOH/H2O solution acidified with either CF3COOH or CF3SO3H leads to the formation of the [Cp*3Mo3(μ-O)2(μ-OH)4]2+ ion as its trifluoroacetate or trifluoromethanesulfonate salt. The structure of the compound

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::fed9243df4c5be10cf01fe14ede4a529
https://doi.org/10.1002/ejic.200500665