Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Fumitaka Narumi"'
Autor:
Takashi Kajiwara, Nariaki Sasagawa, Nobuji Matsumura, Koichi Natori, Tetsutaro Hattori, Fumitaka Narumi
Publikováno v:
Tetrahedron: Asymmetry. 19:1470-1475
Inherently chiral anti - O , O ′-dibenzyl- and anti - O , O ′-dibutyl- p - tert -butylthiacalix[4]arenes 4 and 6 are resolved as ( S )-2-methoxy-2-(naphthalen-1-yl)propionic esters by flash chromatography. The absolute stereochemistries were dete
Publikováno v:
Tetrahedron Letters. 48:6281-6285
A net anti -selective dialkylation of the proximal hydroxy groups of thiacalix[4]arene 2 is achieved for the first time via the initial protection of the two proximal hydroxy groups of compound 2 with Tf moieties by intramolecular rearrangement of ea
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 258:172-177
Composite materials were prepared by intercalating cationic porphyrinato cobalt complexes with the substituents of the quaternary ammonium salt of heterocyclic amine into a montmorillonite interlayer. Using these clay interlayer-fixed porphyrinato co
Publikováno v:
Tetrahedron: Asymmetry. 16:793-800
Inherently chiral anti-O,O′-dibenzyl-p-tert-butylcalix[4]arene 1 was resolved as the (S)-2-methoxy-2-(naphthalen-1-yl)propionic ester by flash chromatography. Conversely, the anti-O,O′-dibutyl analogue 2 was resolved as the (Sa)-2′-methoxy-1,1
Autor:
Toru Onodera, Tetsutaro Hattori, Hiroshi Kameyama, Fumitaka Narumi, Nobuji Matsumura, Chizuko Kabuto, Hiroshi Katagiri, Sotaro Miyano
Publikováno v:
Tetrahedron. 60:7827-7833
Treatment of readily available O,O′-1,1,3,3-tetraisopropyldisiloxane-1,3-diyl-bridged p-tert-butylthiacalix[4]arene ( 1 ) with tri(ethylene glycol) di-p-tosylate and subsequent desilylation gave O,O′-bridged thiacalix[4]crown 3 in an excellent yi
Autor:
Masuhiro Abe, Fumitaka Narumi, Kingo Itaya, Katsuhiko Nishiyama, Kenji Sashikata, Soichiro Yoshimoto, Isao Taniguchi
Publikováno v:
Langmuir. 19:8130-8133
p-tert-Butylcalix[4]arene-1,3-dithiol (BCAD) was synthesized to prepare a functionalized surface for host-guest molecular recognition by immobilizing it on the Au(100)-(1 × 1) surface in 0.05 M HClO 4 . In situ scanning tunneling microscopy (STM) wa
Autor:
Fumitaka Narumi, Naoya Morohashi, Nobuji Matsumura, Hiroshi Kameyama, Nobuhiko Iki, Sotaro Miyano
Publikováno v:
Tetrahedron Letters. 43:621-625
Treatment of calix[4]arenes with 1,3-dichloro-1,1,3,3-tetraisopropyldisiloxane using imidazole as a base yielded O , O ′-bridged calixarenes in excellent yields, which were subsequently treated with an alkyl halide/base to give O ″, O ‴-dialkyl
Autor:
Nobuhiko Iki, Toyohisa Fujimoto, Tomohiro Suzuki, Naoya Morohashi, Sotaro Miyano, Fumitaka Narumi
Publikováno v:
Tetrahedron Letters. 40:7337-7341
Novel molecular receptors, cone- and 1,3-alternate-tetracarboxylic acid (3) and syn-A,C-dicarboxylic acid (5), were prepared by hydrolysis of the ester moiety of the tetra- (2) and di-ethers (4), which had been synthesized by regio- and conformation-
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :2745-2750
5,11,17,23-Tetra-tert-butyl-2,8,14,20-tetrathiacalix[4]arene-25,26,27,28-tetrol (TCA) underwent facile tetra-O-alkylation by treatment with ethyl bromoacetate in the presence of an alkali carbonate as base catalyst in DMF or acetone to provide a mixt
Publikováno v:
Bulletin of the Chemical Society of Japan. 71(7):1597-1603
The ability of tetra(p-t-butyl)tetrathiacalix[4]arenetetrol (TCA, H4L), a cyclic tetramer of p-(t-butyl)phenol bridged with four epithio groups, to bind metal ions was investigated via a solvent extraction study. Although tetra(p-t-butyl)calix[4]aren