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pro vyhledávání: '"Fule Wu"'
The reactivity of the 2-phenylpyridine-derived [Cp*CoI(phpy-κC,N)] metallacycle towards Et3SiH and hydrides was evaluated. The treatment of the same Co(III) complex with Na[BHEt3] resulted in its decomposition into cobalt nanoparticles. The hydride-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e6bb656b4d0ab7a60d46e9fbeb51af90
Wiley Online Library
Wiley Online Library
Autor:
Lydia Karmazin, Nathalie Kyritsakas, Christophe Deraedt, Laurent Ruhlmann, Jean-Pierre Djukic, Corinne Bailly, Nolwenn Le Breton, Yann Cornaton, Sylvie Choua, Fule Wu
Publikováno v:
Organometallics. 40:2624-2642
Recent reports have identified Cp*Co-based complexes as powerful catalysts for aromatic C-H bond activation under oxidative conditions. However, little is known about the speciation of Cp*Co species during catalysis. We now show that key intermediate
Publikováno v:
Zeitschrift für Naturforschung B. 75:851-857
Treatment of [(η 6-p-cymene)RuCl2]2 with one equivalent of chlorodiphenylphosphine in tetrahydrofuran at reflux afforded a neutral complex [(η 6-p-cymene)RuCl2(κ 1-P-PPh2OH)] (1). Similarly, the reaction of [Ru(bpy)2Cl2·2H2O] (bpy = 2,2′-bipyri
Publikováno v:
Journal of Coordination Chemistry. 73:1314-1324
Treatment of [RuCl2(PPh3)3] with N-(β-aminoethyl)-γ-aminopropylmethylbimethoxysilane (L1) in tetrahydrofuran at room temperature gave a mononuclear ruthenium(II) complex [Ru(PPh3)2Cl2 (κ2-N,N-L1)] (1). Condensation of γ-aminopropyltriethoxysilane
Publikováno v:
Journal of Organometallic Chemistry. 885:1-6
Condensation of 3-aminopropyltrimethoxysilane and chlorodiphenylphosphine in the molar ratio of 1:1 and 1:2 in the presence of Et3N in toluene afforded aminophosphine (CH3O)3Si(CH2)3NHPPh2 (L1) and bisphosphinoamine (CH3O)3Si(CH2)3N(PPh2)2 (L2) with
Autor:
Mélanie Boucher, Corinne Bailly, Lydia Karmazin, Jean-Pierre Djukic, Julia Contreras-García, Christophe Deraedt, Fule Wu, Yann Cornaton
Publikováno v:
Organometallics
Organometallics, American Chemical Society, 2020, 39 (14), pp.2609-2629. ⟨10.1021/acs.organomet.0c00253⟩
Organometallics, American Chemical Society, 2020, 39 (14), pp.2609-2629. ⟨10.1021/acs.organomet.0c00253⟩
International audience; The base-assisted cyclometallation of 2-phenylpyridine (2-phpyH) by Cp*Co(III) was holistically addressed both theoretically and experimentally. Combined DFT and DLPNO-CCSD(T) methods assisted by QTAIM-based noncovalent intera
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cbf777fca2cabbda7dd9046a5ea0a618
https://hal.archives-ouvertes.fr/hal-03092632
https://hal.archives-ouvertes.fr/hal-03092632
Publikováno v:
Zeitschrift für Naturforschung B. 73:329-335
Treatment of the bidentate Schiff base 2-[(2,6-diisopropyl-phenylimino)-methyl]-phenol (HL1) with one equivalent of (Et4N)[RuCl4(MeCN)2] in the presence of triethylamine afforded (Et4N)[RuCl3(κ 2-N,O-L1)(MeCN)] (1), which reacted with two equivalent
Publikováno v:
Zeitschrift für Naturforschung B. 73:161-166
Treatment of [(arene)Ru(μ-Cl)Cl]2 with Ph2P(S)NH(2-py) in the presence or absence of base gave two arene-ruthenium(II) complexes [(η 6-p-cymene)Ru{κ 2-N,N-Ph2P(S)N(2-py)}Cl] (1) and [(η 6-benzene)Ru{κ 1-N-Ph2P(S)NH(2-py)}Cl2] (2), which have bee
Publikováno v:
Inorganica Chimica Acta. 471:718-723
Treatment of Ru(NO)Cl3·xH2O with 1 equiv. bidentate Schiff bases in the presence of triethylamine in DMF/THF afforded a series of anionic ruthenium(II) nitrosyl complexes of the type [Et3NH][Ru(κ2-N,O-LR)(NO)Cl3] (HLR = 2-butyliminomethyl-phenol 1,
Publikováno v:
Journal of Organometallic Chemistry. 855:33-43
Condensation of γ-aminopropyltriethoxysilane and substituted salicylaldehydes in ethanol afforded three new Schiff-base compounds [(EtO)3Si(CH2)3N=CHArOH] (Ar = C6H4, L1H; C6H3(4-Cl), L2H; C6H2(2,4-tBu2), L3H). Treatment of [Ru(NO)Cl3⋅xH2O] with L