Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Fritz S. Allen"'
Publikováno v:
Biopolymers. 23:2639-2659
The first-neighbor approximation for the representation of double-stranded polynucleotide CD has been widely applied. Two apparently different formalisms have appeared. We discuss and compare those formalisms and show them to be identical. We present
Publikováno v:
Analytical chemistry. 70(13)
The ideal quality control method for pharmaceutical products should be capable of rapid nondestructive testing of intact tablets or capsules. Raman spectroscopy using near-infrared excitation is shown to be capable of obtaining useful spectral data d
Publikováno v:
Biopolymers. 20:1337-1382
We have synthesized and studied the CD spectra of five new double-stranded RNA polymers: poly[r(A-G)·r(C-U)], poly[r(A-U-C)·r(G-A-U)], poly[r(A-C-U)·r(A-G-U)], poly[r(A-A-C)·r(G-U-U)], and poly[r(A-C-C)·r(G-G-U)]. Together with previously publis
Autor:
Fritz S. Allen, Douglas R. C. Priore
Publikováno v:
Biopolymers. 18:1809-1820
We have considered whether or not the tertiary structure of a biomolecule is the same in a crystal (or an oriented film) as it is in solution. A methodology has been developed for comparing polarized absorption spectra obtained from a solid-state sam
Autor:
Fritz S. Allen, Douglas R. C. Priore
Publikováno v:
Computers & Chemistry. 4:103-106
We present a nonlinear programming technique to test for structural congruency between samples in an oriented film and in solution. We postulate that the structures are congruent and that the solid state and solution polarized absorption spectra are
Autor:
Fritz S. Allen, Light K. Sun
Publikováno v:
The Journal of Chemical Physics. 68:3433-3439
When aqueous solutions of macromolecules are placed in a square, pulsed, orienting electric field they frequently become dichroic and birefrigent. By following the rise of the optical anisotropy as a function of time after application of the pulse on
Publikováno v:
Computers & Chemistry. 5:101-105
A digital procedure has been formulated which is functionally equivalent to phase sensitive detection. The procedure is explained and an application in
Autor:
Kern L. Nuttall, Fritz S. Allen
Publikováno v:
Inorganica Chimica Acta. 91:243-246
Hydrogen selenide ion (HSe − ) reacts with oxygen in the following manner: HSe − + 1/2O 2 → Se o + OH − . Interest in the kinetics of this reaction comes from the fact that selenide is an important product in the metabolism of the essential t
Autor:
Fritz S. Allen, Edward V. Thomas
Publikováno v:
Computers & Chemistry. 1:251-255
The technique of linear programming is a very powerful and widely applied numerical method. In general, chemists have not made use of this tool. Here we present a simple example which shows the superiority of a linear programming based fitting proces
Autor:
Fritz S. Allen, Dawen Ding
Publikováno v:
Biochimica et Biophysica Acta (BBA) - Nucleic Acids and Protein Synthesis. 610:72-80
CD studies of known sequence DNA-like polynucleotide-Hg2+ complexes have established a cross-strand binding of Hg2+ to the two thymines of the base-paired first-neighbor unit TpA, as the type I binding mode of poly[d(A-T) · d(A-T)] and other polynuc