Zobrazeno 1 - 10
of 111
pro vyhledávání: '"Friedrich-Wilhelm Grevels"'
Autor:
Saltuk Saldamli, Jürgen Jacke, Christian W. Lehmann, Richard Goddard, Saim Özkar, Friedrich-Wilhelm Grevels
Publikováno v:
Organometallics. 24:4613-4623
Continued irradiation of W(CO)6 in the presence of excess bis(trimethylsilyl)ethyne (btmse) in n-hexane solution yields W(CO)5(η2-btmse) as the sole product, with quantum yields of 0.66 and 0.69 at λexc = 365 and 313 nm, respectively. Cr(CO)6 behav
Autor:
Winfried Roseboom, Erica J. Lyon, Rudolf K. Thauer, Simon P J Albracht, Eckhard Bill, Friedrich-Wilhelm Grevels, Seigo Shima, Reinhard Boecher
Publikováno v:
Journal of the American Chemical Society, 126, 14239-14248. American Chemical Society
The iron-sulfur-cluster-free hydrogenase Hmd (H(2)-forming methylenetetrahydromethanopterin dehydrogenase) from methanogenic archaea has recently been found to contain one iron associated tightly with an extractable cofactor of yet unknown structure.
Publikováno v:
Organometallics. 22:1696-1711
The photolysis of Fe(CO)3(η4-s-cis-1,3-butadiene) (1) and Fe(CO)4(η2-1,3-butadiene) (2), formerly studied in low-temperature matrixes, is reexamined in cyclohexane solution at ambient temperature using time-resolved IR spectroscopy in the ν(CO) re
Autor:
Klaus Kerpen, and Werner E. Klotzbücher, Kurt Schaffner, Friedrich-Wilhelm Grevels, Ceyhan Kayran and, Richard Goddard and, Bruno Weimann, Saim Özkar
Publikováno v:
Organometallics. 20:4775-4792
Photolysis of M(CO)4(iprop-dab) (1, M = W; 2, M = Mo; iprop-dab = 1,4-diisopropyl-1,4-diazabuta-1,3-diene) in the presence of (E)-cyclooctene (eco) afforded high yields of the unprecedented olefin-substituted derivatives fac-M(CO)3(iprop-dab)(η2-eco
Publikováno v:
Journal of Organometallic Chemistry. 587:122-126
Cycloalkylated ferrocene derivatives, potentially useful as liquid burning rate modifiers for the HTPB/AP-based composite rocket propellants, were synthesized by the Friedel–Crafts alkylation of ferrocene with Z -cyclooctene or cyclohexene in the p
Autor:
Klaus Angermund, Volker Skibbe, Werner E. Klotzbücher, Christian W. Lehmann, Kurt Schaffner, Franz Mark, Carl Krüger, Saim Özkar, Jürgen Jacke, Friedrich-Wilhelm Grevels
Publikováno v:
Organometallics. 18:3278-3293
The photochemical conversion of W(CO)6 (1) into a trans-W(CO)4(η2-olefin)2 complex has been investigated using (E)-cyclooctene (eco) as a model olefin possessing extraordinary coordination properti...
Autor:
Graham Russell, Werner E. Klotzbücher, Kurt Schaffner, and Manuella Viotte, Friedrich-Wilhelm Grevels,†, R. E. D. McClung, Klaus Kerpen
Publikováno v:
Journal of the American Chemical Society. 120:10423-10433
Photochemical experiments with Fe(CO)3(η4-1,5-cyclooctadiene) (1) in a 13CO matrix at 10 K, monitored by means of IR spectroscopy, indicate the generation of stereoselectively labeled Fe(CO)2(13CO)(η4-1,5-cyclooctadiene) (1-1a), with 13CO in the ap
Publikováno v:
Inorganica Chimica Acta. 278:83-90
IR spectra of Cr(CO) 4 (bipyridine) and its 13 CO-containing isotopomers were used to calculate all the stretching and interaction CO force constants and the normal coordinates of the CO stretching vibrations. Resonance Raman (rR) spectra of Cr(CO) 4
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :215-220
Samples of Cr(CO)4(bpy) (bpy = 2,2′-bipyridine) with natural abundance of 13CO and with 16 and 79% 13CO enrichment, respectively, were reduced to the corresponding radical anion, [Cr(CO)4(bpy)]˙– and studied by EPR and IR spectroscopies. Electro
Autor:
Wafa Abdelqader, Saim Özkar,† and, Friedrich-Wilhelm Grevels,‡, Nihad Bekir Peynircioglu, Dietmar Chmielewski
Publikováno v:
Organometallics. 15:604-614
Chromium carbonyl photocatalyzed hydrosilylation of 1,3-butadiene, trans-1,3-pentadiene, 2,3-dimethyl-1,3-butadiene, 2-methyl-1,3-butadiene, trans-2-methyl-1,3-pentadiene, and 1,3-cyclohexadiene wi...