Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Frenio A. Redeker"'
Publikováno v:
Analytical chemistry. 94(34)
Simultaneous elemental detection of F and Cl offers quantitation of fluorinated and chlorinated compounds and their transformation products without compound-specific standards. Despite wide-ranging applications, this capability has been hindered by f
Publikováno v:
Angewandte Chemie International Edition. 59:5464-5493
This Review deals with the evolving field of polyhalogen chemistry, specifically polyhalogen anions (polyhalides). In addition to a historical outline, current progress in synthetic approaches towards the formation of polyfluorides, polychlorides, po
Publikováno v:
Angewandte Chemie. 132:5506-5535
Autor:
Alexey Kropman, Helmut Beckers, Sarah E. Zewge, Beate Paulus, Carsten Müller, Sebastian Riedel, Frenio A. Redeker
Publikováno v:
Journal of Fluorine Chemistry. 216:81-88
While homonuclear free trihalide anions and their alkali ion pairs have been thoroughly described experimentally and theoretically, the coverage of their heteronuclear relatives in the literature remains fragmentary. This might be merely a consequenc
Publikováno v:
Chemical Communications. 53:12958-12961
Here we discuss the reaction products of laser ablated alkali chlorides and elemental chlorine. Salt ablation using this technique combined with matrix-isolation spectroscopy allows for the formation and characterization of novel anionic species. The
Autor:
Stefan Mattsson, Sebastian Riedel, Frenio A. Redeker, Carsten Müller, Beate Paulus, Helmut Beckers
Publikováno v:
Chemistry – A European Journal.
The cohesive energy of α-fluorine, with C2/c space group symmetry, was calculated at benchmark quality by applying the method of increments. The known experimental X-ray structure data needed to be refined, since the reported intramolecular bond len
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
Molecular alkali tetrafluorido aurate ion pairs M[AuF4] (M=K, Rb, Cs) are produced by co‐deposition of IR laser‐ablated AuF3 and MF in solid neon under cryogenic conditions. This method also yields molecular AuF3 and its dimer Au2F6. The products
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3e815737b403146a45d7e7ae43bc6f1b
Autor:
Stefan, Mattsson, Beate, Paulus, Frenio A, Redeker, Helmut, Beckers, Sebastian, Riedel, Carsten, Müller
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 25(13)
The cohesive energy of α-fluorine, with C2/c space group symmetry, was calculated at benchmark quality by applying the method of increments. The known experimental X-ray structure data needed to be refined, since the reported intramolecular bond len
Publikováno v:
RSC Advances. 5:106568-106573
IR laser ablation was used for the systematic matrix-isolation investigation of reaction products of alkali metal fluorides and fluorine. New insights about periodic trends in the reaction behaviour of alkali metals and the formation as well as the p
Autor:
Alejandra Ramirez-Caro, Frenio A. Redeker, Stefanie Bierwirth, Peter Bogdanoff, Klaus Ellmer, Sebastian Fiechter
Publikováno v:
ECS Meeting Abstracts. :1895-1895
Due to the high energy density of hydrogen it could play an important role as energy storage medium replacing fossil fuels in the future. To produce it in large quantities “artificial leaf”-type structures could be used converting solar light int