Výsledky vyhledávání - "Frederick V. Sloop"

Sequestration of trivalent americium and lanthanide nitrates with bis-lactam-1,10-phenanthroline ligand in a hydrocarbon solvent

Autor: Yana Karslyan, Frederick V. Sloop, Alena Paulenova, Santa Jansone-Popova, Ilja Popovs, Bruce A. Moyer, Lætitia H. Delmau

Publikováno v: RSC advances. 9(46)

Efficient separation of minor actinides and lanthanides from used nuclear fuel could potentially lead to the development of sustainable nuclear fuel cycles. Herein, we report an in-depth study on selectivity and speciation in the extraction of the tr

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1425f7d89360bf6902bbf71650aca957
https://pubmed.ncbi.nlm.nih.gov/35528590

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Bis-lactam-1,10-phenanthroline (BLPhen), a New Type of Preorganized Mixed N,O-Donor Ligand That Separates Am(III) over Eu(III) with Exceptionally High Efficiency

Autor: Santa Jansone-Popova, Vyacheslav S. Bryantsev, Ilja Popovs, Madeline M. Dekarske, Radu Custelcean, Bruce A. Moyer, Alexander S. Ivanov, Frederick V. Sloop

Publikováno v: Inorganic chemistry. 56(10)

We report a new family of preorganized bis-lactam-1,10-phenanthroline (BLPhen) complexants that possess both hard and soft donor atoms within a convergent cavity and show unprecedented extraction strength for the trivalent f-block metal ions. BLPhen

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::def4d6f7063f4299b61721f09c5d95be
https://pubmed.ncbi.nlm.nih.gov/28471188

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Enhanced liquid–liquid anion exchange using macrocyclic anion receptors: effect of receptor structure on sulphate–nitrate exchange selectivity

Autor: James A. Shriver, Tamara J. Haverlock, Dustin E. Gross, Manuel Marquez, Lætitia H. Delmau, Jonathan L. Sessler, Bruce A. Moyer, Hyun-Ah Kang, Vincent M. Lynch, Christopher J. Fowler, Kristin Bowman-James, Frederick V. Sloop, Nathan L. Bill, Diadra M. Bau, Alamgir Hossain

Publikováno v: Supramolecular Chemistry. 22:653-671

When certain macrocyclic anion receptors are added to a chloroform solution of the nitrate form of a lipophilic quaternary ammonium salt (methyltri-C8,10-ammonium nitrate, Aliquat 336N), the extraction of sulphate from an aqueous sodium nitrate solut

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::14b4ad26720e3f23ddefcb8cd5c90c18
https://doi.org/10.1080/10610271003763263

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Using GC-FID to Quantify the Removal of 4-sec-Butylphenol from NGS Solvent by NaOH

Autor: Bruce A. Moyer, Frederick V. Sloop

A caustic wash of the solvent used in the Next-Generation Caustic-Side Solvent Extraction (NG-CSSX) process was found to remove the modifier breakdown product 4-sec-butylphenol (SBP) with varying efficiency depending on the aqueous NaOH concentration

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::606be3150ec4836468069aff8fb9bb78
https://doi.org/10.2172/1185680

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Boron-loaded silicone rubber scintillators

Autor: M.A. Miller, Zane W. Bell, Frederick V. Sloop, L. Maya, Gilbert M. Brown

Publikováno v: IEEE Transactions on Nuclear Science. 51:1773-1776

Silicone rubber has received attention as an alternative to polyvinyltoluene in applications in which the scintillator is exposed to high doses of radiation because of the increased resistance of the rubber to the formation of blue-absorbing color ce

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4d1ccb78dbdcf0e7a2ed58c169be4e14
https://doi.org/10.1109/tns.2004.832600

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Next Generation Solvent (NGS): Development for Caustic-Side Solvent Extraction of Cesium

Autor: Lætitia H. Delmau, Arbin Rajbanshi, Peter V. Bonnesen, Frederick V. Sloop, Neil J. Williams, Bruce A. Moyer, Denise L Lee, Talon G. Hill, Dale D. Ensor, Stephanie H. Bruffey, Joseph F Birdwell Jr, Erica L. Stoner, Nathan C. Duncan, Patricia L. Szczygiel, Benjamin D. Roach

This report summarizes the FY 2010 and 2011 accomplishments at Oak Ridge National Laboratory (ORNL) in developing the Next Generation Caustic-Side Solvent Extraction (NG-CSSX) process, referred to commonly as the Next Generation Solvent (NGS), under

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a13a64224551cc1a9de7026735248b81
https://doi.org/10.2172/1237596

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Synthesis of 3-(triethylstannyl)propanoic acid: An organotin mass label for DNA

Autor: Richard A. Sachleben, Frederick V. Sloop, K. B. Jacobson, Gilbert M. Brown, Robert S. Foote

Publikováno v: Bioconjugate Chemistry. 4:406-409

The synthesis of 3-(triethylstannyl)propanoic acid (TESPA), an organometallic reporter group that enables the mass labeling of oligonucleotides with stable isotopes of tin, is described. Synthesized from commercially available isotopically-enriched S

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2dce253c5996cd550820f9f2ba8d66fe
https://doi.org/10.1021/bc00023a017

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