Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Frederick S. Dainton"'
Publikováno v:
J. Chem. Soc., Faraday Trans. 2. 72:2019-2023
Publikováno v:
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 71:2377
The reactions of hydrogen atoms in 6 mol dm–3 H2SO4 have been studied over the temperature range 190–280 K, using a pulse-radiolysis technique. The reactions with Mn2+ and with propan-2-ol show Arrhenius behaviour, with rate parameters: A=(1.8 ±
Publikováno v:
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. 69:243
Reaction of the hyper-reduced metal ions Ni+, Co+ and Cd+ with N2O produces N2 and a hyper-oxidised state M(III) of the metal ion by oxygen atom transfer. When formate is present a chain reaction occurs showing that CO–2 reduces M2+, and that M(III