Zobrazeno 1 - 10
of 23
pro vyhledávání: '"Fred H. Greenberg"'
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 7, Pp 947-950 (2016)
In the title compound, C34H28O4, the cyclohexadiene ring has a screw-boat conformation with a torsion angle between the double bonds being on average ca 15° [15.2 (3) and −15.3 (3) in the two independent molecules]. All four phenyl rings in both m
Externí odkaz:
https://doaj.org/article/c7ebc028e6e04cf18ff9d9e0215fa4cd
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 7, Pp 1054-1059 (2016)
The title compound, C15H11NO4, crystallizes in two polymorphic forms, centrosymmetric monoclinic and chiral orthorhombic. The geometry of the molecules in the two polymorphs is slightly different, possibly due to intermolecular interactions. There ar
Externí odkaz:
https://doaj.org/article/1772f7e0d6ba427e812ba4732d910a63
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 7, Pp o487-o488 (2015)
The title molecule, C26H16O2, crystallizes as a molecular crystal with no strong intermolecular interactions (the shortest C—H...O contact is longer than 3.4 Å). Two flat acenaphthylene groups of neigboring 1,2-dibenzoylacenaphthylene molecules ar
Externí odkaz:
https://doaj.org/article/9d1bf1b736e14effac5d22a98d89e8d8
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications
Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 7, Pp 947-950 (2016)
Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 7, Pp 947-950 (2016)
In the title compound, C34H28O4, the cyclohexadiene ring has a screw-boat conformation. All four phenyl rings in the two independent molecules are arranged in a propeller-like conformation. The two molecules exhibit S,R- and R,S- chirality an
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 7, Pp o487-o488 (2015)
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 7, Pp o487-o488 (2015)
The title molecule, C26H16O2, crystallizes as a molecular crystal with no strong intermolecular interactions (the shortest C—H...O contact is longer than 3.4 Å). Two flat acenaphthylene groups of neigboring 1,2-dibenzoylacenaphthylene molecules ar
Autor:
Fred H. Greenberg
Publikováno v:
Journal of Chemical Education. 77:505
An experiment for the sophomore organic course is described in which dibenzoylethylene is treated with hydriodic acid in acetone at room temperature to obtain dibenzoylethane rather than the expected dibenzoyliodoethane. Advantages are a short reacti
Autor:
Fred H. Greenberg
Publikováno v:
Journal of Chemical Education. 73:1043
The synthetic sequence involving the oxidation of fluorene to fluorenone and the reduction of fluorenone to fluorenol can be extended by preparing the title compounds via the intermediate 9-chlorofluorene. The latter is obtained by heating fluorenol
Autor:
Fred H. Greenberg
Publikováno v:
Journal of Chemical Education. 69:654
A demonstration of solubility by comparing gasoline additives containing methanol and isopropyl alcohol.
Autor:
Fred H. Greenberg
Publikováno v:
Journal of Chemical Education. 69:320
Autor:
Fred H. Greenberg
Publikováno v:
Journal of Chemical Education. 67:611
Illustrates charge delocalization of an ambident anion in an SN2 reaction, the comparative deshielding of oxygen and nitrogen in proton NMR, and the use of the NMR integral in assessing isomer distribution.