Zobrazeno 1 - 10
of 26
pro vyhledávání: '"František Považanec"'
Publikováno v:
Tetrahedron: Asymmetry. 17:1629-1637
A new synthesis of enantiomerically highly enriched N-substituted furoylalanines has been developed. This process involves the combination of crystallisation induced asymmetric transformation (CIAT) and a conjugate addition of N-nucleophiles to furoy
Publikováno v:
Tetrahedron: Asymmetry. 16:1927-1934
Acid-catalyzed lactonization in dilute hydrochloric acid of N-substituted 2-amino-4-aryl-4-hydroxybutanoic acids with electron donating aryl substituents is stereoconvergent. The stereochemical outcome is controlled by the precipitation of little sol
Publikováno v:
Tetrahedron Letters. 46:975-978
CIAT of aza-Michael adducts allows simultaneous build up of two stereocenters. A consequent short and efficient synthesis affords simple access to the both antipodes of various conformationally restricted homophenylalanines.
Publikováno v:
Tetrahedron Letters. 41:5257-5260
A highly stereoselective reduction of γ-oxo-α-amino acids by sodium borohydride in the presence of a catalytic amount of manganese(II) chloride gives syn -γ-hydroxy-α-amino acids. Enantiomerically pure syn -(2 S ,4 R ,1′ S )-4-aryl-4-hydroxy-2-
Autor:
Peter Baran, Martin Breza, Guido Kickelbick, N. Pronayova, Peter Šafář, Jozef Kožíšek, František Považanec
Publikováno v:
Scopus-Elsevier
5-[(2-Furyl)methylidene]-2,2-dimethyl-1,3-dioxane-4,6-dione (1a) treated with equimolar amount of pyrrolidine or hexahydroazepine afforded 5-(pyrrolidine)- (2a) or 5-[(hexahydro- azepine-1-yl)-2-hydroxypenta-2,4-dien-1-ylidene]-2,2-dimethyl-1,3-dioxa
Publikováno v:
Collection of Czechoslovak Chemical Communications. 62:1105-1113
(5-Bromo-2-furyl)methylidenemalonodinitrile (1) reacted with substituted aromatic amines under formation of (5-N-arylamino-2-furyl)methylidenemalonodinitriles 2a-2h whereas no reaction was observed with N-alkyl-N-phenylamines. Derivatives of 2-cyano-
Publikováno v:
Chemical Papers. 67
Straightforward preparation of enantiomerically highly enriched N-substituted aroylalanines has been developed. This process involves the combination of crystallization-induced asymmetric transformation and a conjugate addition of N-nucleophiles to t
Autor:
Ján Cvengroš, František Považanec
Publikováno v:
Bioresource Technology. 55:145-150
Rapeseed oil methyl esters are important alternative diesel fuels based on renewable sources. A discontinuous plant production of methyl esters (ME) is described using two-stage low-temperature transesterification of cold-pressed rapeseed oil with me
Publikováno v:
Collection of Czechoslovak Chemical Communications. 59:2481-2492
Reaction of derivatives of 2-furancarbaldehyde or 2-acetylfuran with malononitrile, methyl cyanoacetate or cyanoacetamide in the presence of secondary amines afforded derivatives of 2-amino-3-furancarboxylic acid in 45 - 88% yields.
Publikováno v:
Collection of Czechoslovak Chemical Communications. 58:555-564
(E-2-Formyl-3-(2-furyl)propenenitrile (I) reacts with primary aromatic amines under formation of 3-(arylamino)-2-[5-(arylamino)-2-oxo-3-cyclopenten-1-yl]propenenitriles (IVa-IVi). Condensation of I with salts of nitrogen bases in pyridine affords 2-(