Zobrazeno 1 - 10
of 796
pro vyhledávání: '"Frank W., Heinemann"'
Cooperative spin crossover leading to bistable and multi-inert system states in an iron(III) complex
Autor:
Andreas Dürrmann, Gerald Hörner, Dirk Baabe, Frank W. Heinemann, Mauricio A. C. de Melo, Birgit Weber
Publikováno v:
Nature Communications, Vol 15, Iss 1, Pp 1-13 (2024)
Abstract Cooperativity among spin centres has long been the royal road in spin crossover (SCO) research to impose magnetic bistability in terms of thermal hysteresis. In this work we access magnetic multi-inert states of the iron(III) compound {FeL2[
Externí odkaz:
https://doaj.org/article/74bca1af92d140eca9b5dc34f83e3f19
Autor:
Andrey G. Lvov, Max Mörtel, Anton V. Yadykov, Frank W. Heinemann, Valerii Z. Shirinian, Marat M. Khusniyarov
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 15, Iss 1, Pp 2428-2437 (2019)
A new family of photochromic diarylethene-based ligands bearing a 2-(imidazol-2-yl)pyridine coordination unit has been developed. Four members of the new family have been synthesized. The photoactive ligands feature non-aromatic ethene bridges (cyclo
Externí odkaz:
https://doaj.org/article/23ac87dbcbaa4988a06d3c069ed6c9f9
Autor:
Douglas R. Hartline, Sascha T. Löffler, Dominik Fehn, Joseph M. Kasper, Frank W. Heinemann, Ping Yang, Enrique R. Batista, Karsten Meyer
Publikováno v:
Journal of the American Chemical Society. 145:8927-8938
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b8b84be567860c3f726329506a9080fe
https://doi.org/10.1021/jacs.2c12868
https://doi.org/10.1021/jacs.2c12868
Publikováno v:
Inorganic Chemistry. 62:2013-2023
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7e57086a80ee775c201305f5083e6ad4
https://doi.org/10.1021/acs.inorgchem.2c03520
https://doi.org/10.1021/acs.inorgchem.2c03520
Autor:
Martin Keilwerth, Weiqing Mao, Sergio A. V. Jannuzzi, Liam Grunwald, Frank W. Heinemann, Andreas Scheurer, Jörg Sutter, Serena DeBeer, Dominik Munz, Karsten Meyer
Publikováno v:
Journal of the American Chemical Society. 145:873-887
As key intermediates in metal-catalyzed nitrogen-transfer chemistry, terminal imido complexes of iron have attracted significant attention for a long time. In search of versatile model compounds, the recently developed second-generation
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f9a24da30ffaf0274936363a9822891e
https://doi.org/10.1021/jacs.2c09072
https://doi.org/10.1021/jacs.2c09072
Autor:
Annette Grünwald, Bhupendra Goswami, Kevin Breitwieser, Bernd Morgenstern, Martí Gimferrer, Frank W. Heinemann, Dajana M. Momper, Christopher W. M. Kay, Dominik Munz
Publikováno v:
Journal of the American Chemical Society. 144:8897-8901
Whereas triplet-nitrene complexes of the late transition metals are isolable and key intermediates in catalysis, singlet-nitrene ligands remain elusive. Herein we communicate three such palladium terminal imido complexes with singlet ground states. U
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::75f1691493ba58bff545324c5e6e3734
https://doi.org/10.1021/jacs.2c02818
https://doi.org/10.1021/jacs.2c02818
Autor:
Sibylle Frieß, Anna Benyak, Alberto Herrera, Ana M. Escalona, Frank W. Heinemann, Jens Langer, Dominik Fehn, Daniel Pividori, Alexander Grasruck, Dominik Munz, Karsten Meyer, Romano Dorta
Publikováno v:
Inorganic Chemistry. 61:1236-1248
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1be9a64e6b4f4b0d809ce22890877cb2
https://doi.org/10.1021/acs.inorgchem.1c02956
https://doi.org/10.1021/acs.inorgchem.1c02956
Publikováno v:
Chemical Science. 13:11341-11351
Employing the newly developed, hepta-dentate tris(aryloxide) ligand cyclen(Me)(t-Bu,t-BuArOH)3 provides controlled access to the first U(iv/v) hydroxido and U(iv/v/vi) oxido complex pairs in a retained ligand environment.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::525cff2a13e919cc1794dbd6c9ced2ac
https://doi.org/10.1039/d2sc02736d
https://doi.org/10.1039/d2sc02736d
Autor:
Ya-Qiong Zhang, Frank W. Heinemann, Lianpeng Tong, Jiale Liu, Karsten Meyer, Rong-Zhen Liao, Randolph P. Thummel
Publikováno v:
Inorganic Chemistry. 60:17976-17985
Novel cobalt and zinc complexes with the tetradentate ppq (8-(1″,10″-phenanthrol-2″-yl)-2-(pyrid-2'-yl)quinoline) ligand have been synthesized and fully characterized. Electrochemical measurements have shown that the formal monovalent complex [
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::009063cad78cb4ab7afcd70885871df6
https://doi.org/10.1021/acs.inorgchem.1c02539
https://doi.org/10.1021/acs.inorgchem.1c02539
Autor:
Andrew Ozarowski, Adedamola A. Opalade, Timothy A. Jackson, Eva M. Zolnhofer, Karsten Meyer, J. Krzystek, Joshua Telser, Frank W. Heinemann
Publikováno v:
Inorganic Chemistry. 60:17865-17877
Octahedral coordination complexes of the general formula trans-[MX2(R2ECH2CH2ER2)2] (MII = Ti, V, Cr, Mn; E = N, P; R = alkyl, aryl) are a cornerstone of both coordination and organometallic chemistry, and many of these complexes are known to have un
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d952ddd05193673819418d69cdc81b41
https://doi.org/10.1021/acs.inorgchem.1c02471
https://doi.org/10.1021/acs.inorgchem.1c02471