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pro vyhledávání: '"Frank Kukla"'
Publikováno v:
European Journal of Inorganic Chemistry. 2002:1377-1389
The π-allyl complexes [Rh(η3-C3H5)(PR3)2] [PR3 = PiPr2Ph (4), PiPrPh2 (5)], prepared from [RhCl(C8H14)2]2, PR3 and the Grignard reagent C3H5MgBr, react with carboxylic acids and p-toluenesulfonic acid to give the chelate compounds [Rh(κ2-O2CR′)(
Autor:
Christine Hahn, Bettina Windmüller, Matthias Laubender, Frank Kukla, Michael Schneider, Matthias Manger, Marco Bosch, Helmut Werner, Birgit Weberndörfer
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :3549-3558
The reaction of [Rh(η3-C3H5)(PPri3)2] 1 or [Rh(η3-CH2Ph)(PPri3)2] 2 with an equimolar amount of RSO3H (R = Me, p-tolyl, CF3, F, Camph) led to the formation of the monomeric sulfonatorhodium(I) complexes [Rh{η2-O2S(O)R}(PPri3)2] 3–7 in excellent
Autor:
Helmut Werner, Frank Kukla
Publikováno v:
Inorganica Chimica Acta. 235:253-261
The reaction of [RhCl(C2H4)2]2 (1) with PtBu2Me yields the square-planar complex trans-[RhCl(C2H4)(PtBu2Me)2] (2) which upon treatment with H2 gives the dihydride [RhH2Cl(PtBu2Me)2] (3) and ethane. The alkynerhodium(I) compounds trans-[RhCl(HCCR)(