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pro vyhledávání: '"Frank Cuthbert Adam"'
Autor:
Frank Cuthbert Adam, Allen John Elliot
Publikováno v:
Canadian Journal of Chemistry. 55:1546-1557
Simple alkyl sulfides and disulfides have been photolysed at 253.7 nm in dilute rigid glasses of 3-methylpentane, and the reactions which occur both at 77 K and in the glass at higher temperatures have been studied using epr and optical spectroscopy.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::aa9a89f18b54399ae050ab0784de60ef
https://doi.org/10.1139/v77-215
https://doi.org/10.1139/v77-215
Publikováno v:
Canadian Journal of Chemistry. 54:3833-3838
The use of molecular oxygen as a spin trap in rigid glassy hydrocarbon media at 77 K is investigated. By slight warming of the matrix, oxygen is found to effectively scavenge the isolated alkyl radicals produced by γ-irradiation to give RO2•, but
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3ace0f2ec835f23e37ae2fa4f28e4308
https://doi.org/10.1139/v76-551
https://doi.org/10.1139/v76-551
Publikováno v:
Canadian Journal of Chemistry. 56:1856-1863
The optical spectra of the charged ions obtained from γ-irradiation of dilute alkyl mercaptans, sulfides, and disulfides in a variety of dilute rigid glasses are measured at 77 K. The photochemical stability of these ions is determined. A new photoc
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8e08ac46bd58f3e454d214bc58fafdca
https://doi.org/10.1139/v78-302
https://doi.org/10.1139/v78-302
Autor:
Frank Cuthbert Adam, Allen John Elliot
Publikováno v:
Canadian Journal of Chemistry. 52:102-110
Dilute solutions of aliphatic thiols have been prepared and photolyzed at 253.7 nm in 3-methylpentane glasses at 77°K. The major products formed initially are thiyl radicals RS• and hydrogen atoms. Both of these are hot and yield solvent radicals
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::637d589b6cfc96643b5953db0715713d
https://doi.org/10.1139/v74-015
https://doi.org/10.1139/v74-015
Autor:
Frank Cuthbert Adam, Allen John Elliot
Publikováno v:
Chemischer Informationsdienst. 5
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8e495900c46e13f1bd2090846376c6d9
https://doi.org/10.1002/chin.197415123
https://doi.org/10.1002/chin.197415123