Výsledky vyhledávání - "Frank Bottomley"

Synthesis, Characterization, and Thermochemistry of (η1-C13H9)Mn(CO)5 and (η5-C13H9)Mn(CO)3

Autor: Frank Bottomley, Andreas Decken, Andrew J. Mackay, Martin J. Brown

Publikováno v: Organometallics. 21:2006-2009

Reaction of LiC 1 3 H 9 with Mn(CO) 5 Br at -78 °C gave (η 1 -C 1 3 H 9 )Mn(CO) 5 , 2. Thermal rearrangement of 2 yielded (η 5 -C 1 3 H 9 )Mn(CO) 3 , 1, 9,9'-bifluorene, 3, and Mn 2 (CO) 1 0 , 4. The product distribution was controlled by the elec

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9ce76c65e778dafb979255a885ac7b44
https://doi.org/10.1021/om020013g

Zobrazit plný text záznamu

Iron complexes of the dibenzophospholyl ligand: a synthetic and crystallographic study

Autor: Frank Bottomley, C Adam Dyker, Melanie A Neil, Andreas Decken

Publikováno v: Canadian Journal of Chemistry. 80:55-61

Iron complexes bearing the dibenzophospholyl (DBP) ligand have been prepared. Reaction of DBP-Li with CpFe(CO)2Br gave [(µ2-DBP)Fe2Cp2(CO)4]Br and reaction of DBP-Li with CpFe(CO)2I gave [(µ2-DBP)Fe2Cp2(CO)4]I. Reaction of bis(1,1'-dibenzophospholy

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f0b13d65a060e5126eaba41480054247
https://doi.org/10.1139/v01-193

Zobrazit plný text záznamu

Synthesis and characterization of manganese complexes of the dibenzophospholyl ligand

Autor: Frank Bottomley, Andreas Decken, Melanie A Neil

Publikováno v: Canadian Journal of Chemistry. 79:1321-1329

Manganese carbonyl complexes bearing dibenzophospholyl (DBP) and 1-phenyldibenzophosphole (Ph-DBP) ligands have been prepared. Reaction of Li-DBP with Mn(CO)5Br gave (µ2-DBP)(µ2-Br)Mn2(CO)8, while reaction of bis(1,1'-dibenzophospholyl) and Mn2(CO)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e6a27f5c36c32140484c7cda92b95716
https://doi.org/10.1139/v01-124

Zobrazit plný text záznamu

Organometallic Oxides: Oxidation of the Cubane [(η-C5R5)Cr(μ3-O)]4 and the Structures and Magnetic Properties of the Salts {[(η-C5R5)Cr(μ3-O)]4}{tcnq} and {[(η-C5R5)Cr(μ3-O)]4}{BF4}

Autor: Frank Bottomley, and David A. Summers, Victor Sanchez, Robert C. Thompson, Andreas Decken, Daryl P. Allen, Robert W. Day

Publikováno v: Organometallics. 20:1840-1848

Differential pulse and current voltammetry for the cubane-like clusters [(η-C5R5)Cr(μ3-O)]4 (R = H, Me; R5 = H4Me) showed that [(η-C5H4Me)Cr(μ3-O)]4 and [(η-C5Me5)Cr(μ3-O)]4 were oxidized to {[(η-C...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::cd1b7d400df2196ef8e95de73c678239
https://doi.org/10.1021/om001067y

Zobrazit plný text záznamu

Organometallic oxides: preparation of the cluster [(η-C5Me5)Mo]4O7 by reduction of [(η-C5Me5)MoCl(O)]2(μ-O) or (η-C5Me5)MoCl2(O)

Autor: Robert C. Thompson, Olusola O. Womiloju, Zhiqiang Xu, Victor Sanchez, Frank Bottomley

Publikováno v: Canadian Journal of Chemistry. 78:383-394

Reduction of [(η-C5Me5)MoCl(O)]2(μ-O) or (η-C5Me5)MoCl2(O) with sodium or magnesium amalgam, magnesium turnings, or tributyltin hydride produced [(η-C5Me5)Mo]4O7, with [(η-C5Me5)Mo(O)(μ-O)]2 as a co-product. [(η-C5Me5)Mo]4O7 was characterized

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3335f8085d380f893220f5f79f87b871
https://doi.org/10.1139/v00-030

Zobrazit plný text záznamu

Organometallic o×ides: preparation of the cluster [(η-C5Me5)Mo]4O7 by reduction of [(η-C5Me5)MoCl(O)]2(μ-O) or (η-C5Me5)MoCl2(O)

Autor: Robert C. Thompson, Victor Sanchez, Zhiqiang Xu, Olusola O. Womiloju, Frank Bottomley

Publikováno v: Canadian Journal of Chemistry. 78:383-394

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f656ce8b1e79a16a8ae99d680c22e1df
https://doi.org/10.1139/cjc-78-3-383

Zobrazit plný text záznamu

Organometallic Oxides: Preparation and Properties of the Clusters [(η-C5Me5)V(μ3-O)]4 and [(η-C5Me5)V]4(μ-O)6 by Reductive Aggregation of (η-C5Me5)VCl2(O)

Autor: Robert W. Day, David A. Summers, Andreas Decken, Colin D. Abernethy, Frank Bottomley, Robert C. Thompson

Publikováno v: Organometallics. 18:870-879

Reduction of Cp*VCl2(O) (Cp* = η-C5Me5) by the powerful reductants sodium, potassium, magnesium, or calcium or the amalgams of these metals gave a mixture of the black cubane-like cluster [Cp*V(μ3-...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d0bbca83dc4272ed4f1348d533a18bbd
https://doi.org/10.1021/om9807809

Zobrazit plný text záznamu

Organometallic Halides: Preparation and Physical and Chemical Properties of Tris[(η-pentamethylcyclopentadienyl)dichlorovanadium], [(η-C5Me5)V(μ-Cl)2]3

Autor: Andreas Decken, Colin D. Abernethy, Robert C. Thompson, Frank Bottomley

Publikováno v: Organometallics. 16:1865-1869

The cluster [(η-C5Me5)V(μ-Cl)2]3 was synthesized from VCl3(thf)3 and Bun3SnC5Me5. It was oxidized by O2 to give (η-C5Me5)VCl2(O), and by NaN3 to give [(η-C5Me5)VCl(μ-N)]2. X-ray diffraction showed that [(η-C5Me5)V(μ-Cl)2]3 had an equilateral t

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::6803c2377fc46e6d9eaad506ea7d3d03
https://doi.org/10.1021/om960482g

Zobrazit plný text záznamu

An investigation of the MAM angle in compounds of general formula [MLn]2(μ-A)

Autor: Frank Bottomley, Sor-Koon Goh

Publikováno v: Polyhedron. 15:3045-3074

The structures of 283 compounds of general formula [MLm](μ-A)[M′L′n] (M, M′ = d-or ƒ-block element, L, L′ = ligands0(s), A = p-block element) with respect to the MAM angle (θ). Molecular orbital (primarily extended Huckel) and statis

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0fdb98093713336c6338764dc27fbbd4
https://doi.org/10.1016/0277-5387(96)00022-8

Zobrazit plný text záznamu

Vyhledávací nástroje:

Upřesnit hledání