Zobrazeno 1 - 10
of 62
pro vyhledávání: '"Franco Piacenti"'
Publikováno v:
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Publikováno v:
Journal of Molecular Catalysis A: Chemical. 172:127-134
The influence of an additional gas on the hydroformylation of cyclohexene in the presence of Co2(CO)6(PBu3)2 has been tested. The rate of the hydroformylation is reduced by the presence of an appropriate amount of dinitrogen, argon or xenon as additi
Publikováno v:
Journal of Organometallic Chemistry. 625:255-267
Phosphine-substituted ruthenium carbonyls have often been used as catalytic precursors in reactions such as the hydrogenation or the hydroformylation of olefins. To collect evidence on the coordination of the olefin as a preliminary step of these rea
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 159:185-195
The behaviour of phosphine substituted ruthenium carbonyl carboxylates in the presence of hex-1-ene has been followed by IR and NMR spectroscopies. The complex Ru4(CO)8(MeCO2)4(PBu3)2 reacts at room temperature with a large excess of hex-1-ene giving
Autor:
Mario Bianchi, Antonella Salvini, Leonardo Pistolesi, Franco Piacenti, Luca Rosi, Piero Frediani
Publikováno v:
Journal of Organometallic Chemistry. 582:218-228
Hydrido ruthenium carbonyl complexes substituted by functionalized phosphines such as H4Ru4(CO)8[P(CH2OCOR)3]4 have been synthesized and tested as catalysts in the hydrogenation of carboxylic acids. These complexes are more active than those reported
Publikováno v:
Inorganica Chimica Acta. 272:141-149
The hydrogenolysis of the acetato group by molecular hydrogen in phosphine-substituted ruthenium(I) and (II) carbonyl carboxylates has been reinvestigated in the presence of Na2CO3 at various temperatures. From mononuclear complexes such as Ru(CO)2(M
Publikováno v:
Journal of Organometallic Chemistry. 535:143-147
Tributylphosphine n-propyl-(Ia) and iso-propyl (Ib) cobalt tricarbonyl have been prepared from NaCo(CO)3(PBu3) and the proper alkyl halide. The behaviour of Ia and Ib under hydroformylation conditions (T = 120–180°C, pCO = 5 atm, pH2 in the presen
Autor:
Cristina Faggi, Franco Piacenti, Mario Nardelli, Mario Bianchi, Sandra Ianelli, Sandro Papaleo, Piero Frediani, Antonella Salvini
Publikováno v:
Scopus-Elsevier
The reaction between Ru(CO) 2 (MeCO 2 ) 2 (PPh 3 ) 2 , or Ru 2 (CO) 4 (MeCO 2 ) 2 (PPh 3 ) 2 , and hydrogen (100 atm) at temperatures between 80 and 160°C has been investigated. The products formed are ruthenium clusters containing PPh 3 , PPh 2 and
Autor:
Mario Nardelli, Mario Bianchi, Leonardo Pistolesi, Franco Piacenti, Luca Rosi, Antonella Salvini, Sandra Ianelli, Piero Frediani
Publikováno v:
Organometallics. 16:482-489
The synthesis and characterization of phosphines containing ester groups P(CH2OCOR)3 (R = CH3−, C2H5−, (CH3)2CH−, (CH3)3C−, (S)-C2H5CH(CH3)−) are reported. The new hydridoruthenium complexes H4Ru4(CO)8[P(CH2OCOR)3]4 (R = CH3−, C2H5−, (C
Publikováno v:
Journal of Organometallic Chemistry. 526:33-41
Propene can be oligomerized using Ru3(CO)12 as catalytic precursor in solution of a hydrogen donor solvent or in the presence of ethylene. Ethylene-propene mixtures undergo oligomerization in the presence of Ru3(CO)12 at 120°C with conversion even h