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pro vyhledávání: '"Franco Alberto Merckling"'
Autor:
Walter Ganci, Peter Rüedi, Urs Ringeisen, G. Przibille, Franco Alberto Merckling, Eric J. M. Meier
Publikováno v:
Helvetica Chimica Acta. 80:421-435
The inhibition of δ-chymotrypsin with optically active, axially and equatorially substituted trans-3-(2,4-dini-trophenoxy)-2,4-dioxa-3λ5-phospbubicyclo[4.4.0]decan-3-ones ( = hexahydro-4H-1,3,2-benzodioxaphosphorin 3-oxides) was investigated. Their
Autor:
Peter Rüedi, Franco Alberto Merckling
Publikováno v:
Tetrahedron Letters. 37:2217-2220
Reaction of the axially substituted trans -3-chloro-2,4-dioxa-3λ 5 -phosphabicyclo[4.4.0]decan-3-one ((±)- 1 ) with O- and S-nucleophiles in the presence of DBN preferentially proceeds with retention at P, whereas the epimeric ration is reversed wi