Using molten salts to probe outer-coordination sphere effects on lanthanide(iii)/(ii) electron-transfer reactions

Autor: Kristen A. Pace, Stosh A. Kozimor, Veronika Mocko, Ping Yang, Jennifer N. Wacker, Francisca R. Rocha, Cecilia Eiroa-Lledo, Molly M. MacInnes, Karah E. Knope, Nickolas H. Anderson, Enrique R. Batista, Ida M. DiMucci, Zachary R. Jones, Bo Li, Maksim Y. Livshits, Benjamin W. Stein

Publikováno v: Dalton Transactions. 50:15696-15710

Controlling structure and reactivity by manipulating the outer-coordination sphere around a given reagent represents a longstanding challenge in chemistry. Despite advances toward solving this problem, it remains difficult to experimentally interroga

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::062f1477d661afcbc458523d9e3fa79c
https://doi.org/10.1039/d1dt02708e

Sunlight-Driven Dehydrogenative Oxidation Photocatalysis by a Mononuclear Complex Acting as both Chromophore and Catalyst

Autor: Weizhong Chen, Francisca R. Rocha, Reginaldo C. Rocha, Brian L. Scott

Publikováno v: Journal of the Brazilian Chemical Society v.31 n.11 2020
Journal of the Brazilian Chemical Society
Sociedade Brasileira de Química (SBQ)
instacron:SBQ
Journal of the Brazilian Chemical Society, Volume: 31, Issue: 11, Pages: 2421-2429, Published: 30 OCT 2020

Under simulated solar irradiation in the visible spectral region, the catalytically active RuIV-oxo species [Ru(O)(bpy)(tppz)]2+ (tppz = tetrapyridylpyrazine, a strongly π-accepting tridentate N, N, N-ligand) is produced directly from a single metal

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1e4a8af617351872ee485e98a36e9fb5
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532020001102421