Bidentate forms of β-triketimines: syntheses, characterization and outstanding performance of enamine–diimine cobalt complexes in isoprene polymerization

Autor: Mohammed N. Alnajrani, Francis S. Mair

Publikováno v: Dalton Transactions. 45:10435-10446

New cationic enamine-β-diimine cobalt complex [LCoBr·THF][BArF] () and its neutral analogue [LCoBr2] () where L = [(2,4,6-Me3-C6H2)NHCMe[double bond, length as m-dash]C{CMe[double bond, length as m-dash](N-2,4,6-Me3(C6H2))}2] and BArF(-) = [{3,5-(C

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::67ca43f58edaebfbd55c19a7592bfa99
https://doi.org/10.1039/c6dt01064d

Synthesis and structural characterization of a nickel(II) precatalyst bearing a β-triketimine ligand and study of its ethylene polymerization performance using response surface methods

Autor: Hassan Arabi, Francis S. Mair, Gholamhossein Zohuri, Nona Ghasemi Hamedani, Andrew Jolleys

Publikováno v: Hamedani, N G, Arabi, H, Zohuri, G H, Mair, F S & Jolleys, A 2013, ' Synthesis and structural characterization of a nickel(II) precatalyst bearing a β-triketimine ligand and study of its ethylene polymerization performance using response surface methods ', Journal of Polymer Science. Part A: Polymer Chemistry, vol. 51, no. 7, pp. 1520-1532 . https://doi.org/10.1002/pola.26522

The reaction of N-(4-(mesitylamino)pent-3-en-2-ylidene)-2,4,6-trimethylbenzenamine (1) with n-butyl lithium and then with N-(2,4,6-trimethyl-phenyl)-acetimidoyl chloride yields a new β-triketimine ligand, N-(4-(mesitylamino)-3-(1-(mesitylimino)ethyl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b7c4c772e35fc57f99c70222ddc2cd96
https://doi.org/10.1002/pola.26522

A New, Flexible N , N , N ‐Tripodal Facially Capping Ligand System: Synthesis and Structural Characterization of β‐Triketimines and Their M(CO) 3 Complexes (M = Cr, Mo, W)

Autor: Alan R. Kennedy, Ian German, Boyang Liu, Arron Sanders, Francis S. Mair, Martyn Brownhill, Donna Barnes, Christopher J. Herbert, Robin G. Pritchard, Katy McBride, Gemma L. Brown, Andrew Jolleys, John E. Warren

Publikováno v: European Journal of Inorganic Chemistry. 2009:1219-1233

Reaction of imidoyl chlorides {Ar*N=CCIR} (Ar* = 2-{iPrC(6)H(4)}, 2,6-{iPr(2)C(6)H(3)}, 2-{MeOC6H4;} R = Me, Ph, {tBu)} with [Li(nacnac)] [nacnac = ({Ar*NCMe)(2)CH]} gives beta-triketimines L, most of which exist in solution in equilibrium with their

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e8bf7c3a2b60c1cadb0df3bf6f89fde0
https://doi.org/10.1002/ejic.200801022

C2- and Cs-symmetric diamidodichlorotitanium complexes: Syntheses, structures and 1-hexene polymerization catalysis

Autor: Rebecca J. Woods, Frank Heatley, Francis S. Mair, Robin G. Pritchard

Publikováno v: Journal of Organometallic Chemistry. 690:2078-2086

The complexes l-[CMe2{CHMeN(2-Pri-C6H4)}2TiCl2] (2) and u - [ CMe 2 { CHMeN ( 2 , 6 - Pr 2 i C 6 H 3 ) } 2 TiCl 2 ] (3), C2- and Cs-symmetric analogues, respectively, of McConville’s C2v hexene polymerization precatalyst [ ( CH 2 ) 3 { N ( 2 , 6 -

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::76af2fdcf7e2c0e6a40134ca8d0e6534
https://doi.org/10.1016/j.jorganchem.2004.12.029

Palladium co-ordination chemistry of β-diimines: a preparative and structural comparison with α-diimines

Autor: Robin G. Pritchard, Elaine K. Cope-Eatough, Francis S. Mair, Rebecca J. Woods, John E. Warren

Publikováno v: Polyhedron. 22:1447-1454

The co-ordination chemistry of β-diimines has been found to be markedly different from otherwise identical α-diimines, it being significantly more difficult to prepare stable complexes of a variety of transition metal species. Where such species we

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e537fd7a418d8b881dcd3c6a86b3c271
https://doi.org/10.1016/s0277-5387(03)00123-2