Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Francis J. Wodarczyk"'
Autor:
C. Bradley Moore, Francis J. Wodarczyk
Publikováno v:
Chemical Physics Letters. 26:484-488
Absolute rate constants for the reaction Cl + HX → HCl(υ > 0) + X have been determined at 295°K for X = Br and 1 by laser photolysis of Cl2 in flowing Cl2/HX gas mixtures. The rate constants, (7.6 ± 1.8) × 10−12 cm3 molecule−2 sec−1 for X
Publikováno v:
The Journal of Chemical Physics. 67:4476-4482
Molecular bromine has been observed to lase when optically pumped on individual vibration–rotation lines. With no dispersive elements in the laser cavity the output consists of several doublets, corresponding to P‐ and R‐branch transitions from
Publikováno v:
Chemical Physics. 12:65-70
Room temperature experiments have measured the rate of electronic-to-vibrational energy transfer between spin—orbit excited Br(4 2 P 1 2 ) and HF. The Br * + HF quenching rate is very fast, (1.1 ± 0.2) × 10 6 s −1 torr −1 , due to a near reso
Publikováno v:
The Journal of Chemical Physics. 62:2934-2938
The vibrational relaxation of HCl(v=1) by Cl atoms at 294°K has been carefully measured by two different techniques. A discharge‐flow‐tube, laser‐fluorescence method yielded a deactivation rate constant kCl = (8.8±2.6) ×10−12 cm3 molecule
Autor:
Alan B. Harker, Francis J. Wodarczyk
Publikováno v:
Chemical Physics Letters. 62:529-533
The rate of the reactive quenching of metastable Hg(6 3P0) atoms by molecular chlorine was determined by phase-sensitive modulation spectroscopy to be (1.0 ± 0.2) × 10−10 cm3 molecule−1 s−1, corresponding to a quenching cross section of 28 A2
Autor:
E. Bright Wilson, Francis J. Wodarczyk
Publikováno v:
The Journal of Chemical Physics. 56:166-176
The gas‐phase microwave spectrum of 1‐pentyne has been investigated in the region 8–40 GHz. The spectrum can be attributed to two rotational isomers in which the methyl group is, respectively, trans and gauche to the acetylene substituent. The
Autor:
Francis J. Wodarczyk, E. Bright Wilson
Publikováno v:
Chemischer Informationsdienst. 3
Autor:
Francis J. Wodarczyk, Stephen R. Leone
Publikováno v:
The Journal of Chemical Physics. 60:314-315