Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Francis C. Rix"'
Autor:
Jonathan Schaefer, Hua Zhou, Eryn Lee, Nikola S. Lambic, Gursu Culcu, Matthew W. Holtcamp, Francis C. Rix, Tzu-Pin Lin
Publikováno v:
ACS Catalysis. 12:11870-11885
Publikováno v:
ACS Catalysis. 6:1518-1532
On the occasion of Professor Maurice Brookhart’s retirement and recent acceptance of the Gabor A. Somorjai Award for Creative Research in Catalysis, we honor his numerous contributions to the fields of organometallic chemistry and catalysis. His tr
Autor:
Jack R. Norton,† and, Francis C. Rix, Nikos Spetseris, Elizabeth T. Papish, Robert D. Williams
Publikováno v:
Journal of the American Chemical Society. 122:12235-12242
We have compared the rate at which a proton is transferred to the hydride ligand of CpW(CO)2(PMe3)H (3) with the rate at which one is transferred to the metal. Qualitative evidence that protonation of the hydride ligand is faster is offered by observ
Publikováno v:
Journal of the American Chemical Society. 119:906-917
The cationic Pd(II) complexes, [(phen)Pd(CH3)(L)]+[BAr‘4]- phen = 1,10−phenanthroline; L = Et2O, Me3SiC⋮CSiMe3; Ar‘ = 3,5-(CF3)2C6H3) catalyze the hydrosilation and dehydrogenative silation of olefins. Hydrosilation of ethylene, tert-butyleth
Publikováno v:
Journal of the American Chemical Society. 118:2436-2448
The β-methyl migratory insertion chemistry of a series of cis-coordinated styrene methyl complexes of palladium [(phen)Pd(CH3)(p-X-C6H4CHCH2)+Ar‘4B- (2X) (phen = 1,10-phenanthroline; X = CF3, Cl, H, CH3, OCH3; Ar‘ = 3,5-(CF3)2C6H3)] has been inv
Mechanistic Studies of the Palladium(II)-Catalyzed Copolymerization of Ethylene with Carbon Monoxide
Publikováno v:
Journal of the American Chemical Society. 118:4746-4764
The microscopic steps responsible for the perfectly alternating copolymerization of ethylene and CO catalyzed by 1,10-phenanthroline (phen) based palladium complexes have been studied. Palladium carbonyl alkyl, carbonyl acyl, ethylene alkyl, and ethy
Autor:
Barbara Milani, Maurice Brookhart, James C. Barborak, Mark I. Wagner, Francis C. Rix, Michael J. Rachita
Publikováno v:
Dalton Transactions. :8977
A mechanistic interpretation of the [(1,10-phenanthroline)Pd(CH(3))(CH(3)CN)](+)[BArF](-) (1a) and [(2,2'-bipyridine)Pd(CH(3))(CH(3)CN)](+)[BArF](-) (1b) (BArF = 3,5-(CF(3))(2)-C(6)H(3)) catalyzed perfectly alternating copolymerization of styrenes wi
Autor:
Francis C. Rix, Maurice Brookhart
Publikováno v:
Journal of the American Chemical Society. 117:1137-1138
Publikováno v:
Journal of the American Chemical Society. 114:5894-5895
Several Pd(II) catalyst systems have been reported which effect prefectly alternating copolymerization of olefins with carbon monoxide to yield polyketones [C(O)CH(R)CH{sub 2}]{sub n}. There has been increasing interest in these polymers, particularl
Autor:
Francis C. Rix, Michael J. Rachita, Mark I. Wagner, Maurice Brookhart, Barbara Milani, James C. Barborak
Publikováno v:
Dalton Transactions: An International Journal of Inorganic Chemistry; Oct2009, Vol. 2009 Issue 41, p8977-8992, 16p