Výsledky vyhledávání - "Francesco Bigoli"

Structure and characterisation of [Pt(Me2pipdt)2][Pt(mnt)2]2 and its unusual magnetic properties associated with a non-regular one-dimensional [Pt(mnt)2] stack

Autor: Samuele Sanna, Paola Deplano, Francesco Congiu, Maria Laura Mercuri, Giorgio Concas, Angela Serpe, Luca Pilia, Francesco Bigoli, Luciano Marchiò

Publikováno v: Chemical Physics Letters. 421:361-366

For electro-oxidation of [Pt(Me 2 pipdt) 2 ][Pt(mnt) 2 ] (Me 2 pipdt N , N ′-dimethyl-piperazine-2,3-dithione; mnt = maleonitrile-2,3-dithiolate) ( 1a ) the novel salt [Pt(Me 2 pipdt) 2 ][Pt(mnt) 2 ] 2 ( 2a ) has been prepared and characterised. 2a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f88366d3bff43b3676e2ae6072145b0d
https://doi.org/10.1016/j.cplett.2006.01.097

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On the Use of the Bis(diiodine) Adduct of 1,4‐Dimethylperhydro‐1,4‐diazepine‐2,3‐dithione (Me 2 dazdt) to Recover Liquid Mercury Producing [Hg(Me 2 dazdt)I 2 ] in a One‐Step Reaction

Autor: Maria Laura Mercuri, Francesco Bigoli, Emanuele F. Trogu, Paola Deplano, Luciano Marchiò, Maria Cristina Cabras, Angela Serpe

Publikováno v: European Journal of Inorganic Chemistry. 2004:960-963

Diiodine adducts with cyclic dithio-oxamides, where complexing and oxidising properties coexist in the same molecule, have been shown to be powerful oxidising reagents towards selected metals. Here we describe the reaction of Me2dazdt·2I2 [Me2dazdt

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7d52aa86f9c212c1ffce7a6815916229
https://doi.org/10.1002/ejic.200300525

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A New Conducting Molecular Solid Based on the Magnetic [Ni(dmf)6]2+ Cation and on [Ni(dsit)2]22− (dsit=1,3-dithiole-2-thione-4,5-diselenolate) Showing an Unprecedented Anion Packing

Autor: Angela Serpe, Enric Canadell, Francesco Bigoli, Eugenio Coronado, Simona Curreli, Luca Pilia, Paola Deplano, Maria Laura Mercuri, Maria Angela Pellinghelli, Carlos J. Gómez-García

Publikováno v: Journal of Solid State Chemistry. 168:653-660

The synthesis, X-ray structure, magnetic and transport properties of the compound Ni(dmf) 6 [Ni(dsit) 2 ] 2 (dmf=dimethylformamide, dsit = 1,3-dithiole-2-thione-4,5-diselenolate) are described. This compound crystallizes in the monoclinic space group

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7cfddbfbb90ee00dc551f7366ea3b33c
https://doi.org/10.1006/jssc.2002.9763

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Ion Pair Charge-Transfer Complexes between Anionic and Cationic Metal-Dithiolenes [M(II) = Pd, Pt]

Autor: Gloria Pintus, Francesco Bigoli, Paola Deplano, Luca Pilia, Maria Laura Mercuri, Maria Angela Pellinghelli, and Angela Serpe, Emanuele F. Trogu

Publikováno v: Inorganic Chemistry. 41:5241-5248

New [M(R(2)pipdt)(2)](BF(4))(2) salts [R(2)pipdt = N,N'-dialkyl-piperazine-2,3-dithione; M = Pd(II), R = Me and M = Pt(II), R = Me, Et, Pr(i)] bearing redox-active cationic dithiolene complexes have been prepared and characterized. These cations reac

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8f658a8a2f3279ca3e37cb49f9dd16ee
https://doi.org/10.1021/ic025788w

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Nickel dithiolene complexes as a source of a new family of S,S-dinegative chiral ligands R4btimdt = 5,5′-bis(1,3-dialkyl-4-imidazolidine-2-thione-4-thiolate)

Autor: Angela Serpe, Emanuele F. Trogu, Paola Deplano, Simona Curreli, Maria Laura Mercuri, Maria Angela Pellinghelli, Laura Leoni, Francesco Bigoli

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :1985-1991

The reaction of the complex [Ni(Bu2timdt)2] (Bu2timdt = −1 charged 1,3-dibutylimidazolidine-2,4,5-trithione) with polyfunctional phosphines: tp [tp = bis(2-diphenylphosphinophenyl)phenylphosphine] and qp [qp = tris(2-diphenylphosphinophenyl)phosphi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::90c2fabda337776f54a3b70d8d426413
https://doi.org/10.1039/b108471b

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Synthesis, structure and properties of new unsymmetrical nickel dithiolene complexes useful as near-infrared dyes

Autor: Francesco Bigoli, Patrick Cassoux, Emanuele F. Trogu, Paola Deplano, Gloria Pintus, Maria Laura Mercuri, Maria Angela Pellinghelli, Angela Serpe

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :4639-4644

The new unsymmetrical [Bu4N][Ni(Pri2timdt)(dmit)] 4 and [Bu4N][Ni(Pri2timdt)(mnt)] 5 dithiolene complexes (Pri2timdt is the mono-anion of 1,3-diisopropylimidazolidine-2,4,5-trithione; dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate; mnt = maleonitriledit

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::17f21eb610503fcc4170a942dea8a6d3
https://doi.org/10.1039/b006206p

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Novel oxidation and reduction products of the neutral nickel-dithiolene Ni(Pr2itimdt)2 (Pr2itimdt is the monoanion of 1,3-diisopropylimidazolidine-2,4,5-trithione)

Autor: Paola Deplano, Gloria Pintus, Maria Angela Pellinghelli, Maria Laura Mercuri, Jack M. Williams, Emanuele F. Trogu, Gabriella Zonnedda, Francesco Bigoli, Hsien-Hau Wang

Publikováno v: Inorganica Chimica Acta. 273:175-183

Ni(Pr{sup i}{sub 2}timdt){sub 2} (1) (Pr{sup i}{sub 2}timdt is the monoreduced form of 1,3-diisopropylimidazolidine-2,4,5-trithione), which belongs to a new class of nickel-dithiolenes showing remarkably high absorption in the near-IR ({lambda} {appr

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::10b4da1d2fa4888f2cfc6eb21f74a8ab
https://doi.org/10.1016/s0020-1693(97)06007-6

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Synthesis, Crystal and Molecular Structures of the Novel Compounds 4,7-Dithio-5,6Diselenocino- [1,2b:3,4b']-Diimidazolyl-1,3,8,10-Tetrabutyl 2,9-Dithione and -2,9-Diselone

Autor: Simona Marcis, Rita Onnis, Paola Deplano, Francesco Bigoli, Maria Angela Pellinghelli, Emanuele F. Trogu, Maria Laura Mercuri, Ginevra Orru

Publikováno v: Phosphorus, Sulfur, and Silicon and the Related Elements. 136:659-662

The sulfurization reaction with Lawesson's reagent on a series of 1,3-dialkyl imidazolidine-2-selone-4,5-diones in toluene gave depending on the reaction conditions, the compounds 4,7-dithio, 5,6-diselenocino[1,2b:3,4b']diimidazolyl-1,3,8,10-tetraalk

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::99e5fedb087daead8f447e118328c3b9
https://doi.org/10.1080/10426509808042687

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New semiconductors obtained by reaction of 4-imidazoline-2-selonederivatives with TCNQ. Characterization and X-ray structure of (C9H12N4Se)2+(TCNQ)2−3

Autor: Paola Deplano, M. Angela Pellinghelli, Emanuele F. Trogu, Vito Lippolis, Francesco Bigoli, Alberto Girlando, M. Laura Mercuri, Francesco A. Devillanova

Publikováno v: Journal of Materials Chemistry. 8:1145-1150

The charge transfer complexesI, II and III of three new electron donors, 1,1′-ethylenebis(3-methyl-4-imidazoline-2-selone) 1,1,1′-methylenebis(3-methyl-4-imidazoline-2-selone) 2 and 1,3-dimethyl-4-imidazoline-2-selone 3, with TCNQ have been synth

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d39b31acc6d3758a03aad1cf86f6661a
https://doi.org/10.1039/a707223f

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A Spectro- and Conductometric Study of the Reaction of Imidazoline-2-selone Derivatives with Bromine − Crystal Structure of 1,2-Bis(3-methyl-4-imidazolin-2-ylium dibromoselenanide)ethane

Autor: Francesco Bigoli, Maria Laura Mercuri, Vito Lippolis, Francesco A. Devillanova, Paola Deplano, Maria Angela Pellinghelli, Emanuele F. Trogu

Publikováno v: European Journal of Inorganic Chemistry. 1998:137-141

The oxidative addition of Br2 to the imidazoline-2-selone derivatives 1a−c has been studied by spectrophotometric and conductometric techniques. The experimental results clearly indicate that this reaction involves the dications 2a−c, containing

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2fff00f67e22e6477b6ba3f3b13f3dc9
https://doi.org/10.1002/(sici)1099-0682(199801)1998:1<137::aid-ejic137>3.0.co

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