Zobrazeno 1 - 10
of 75
pro vyhledávání: '"François Guibé"'
Publikováno v:
Synlett. 2009:1614-1618
In the reaction with tert-butyloxycarbonyl anhydride (Boc 2 O), N-(o-vinylacetyloxy)benzenesulfonyl allylic amines 4a―c undergo concomitant O to N acyl migration to give N-(o-vinyl-acetyloxy)-N-(o-tert-butoxycarbonyloxy)benzenesulfonyl allylic amin
Publikováno v:
Tetrahedron. 63:3728-3736
trans -(2′,2′-Diphenyl-bicyclopropyl-2-yl)-4,4-dimethyl-5-oxo-pent-2-enoic acid methyl ester 9 , undergoes 3- exo - trig cyclisation in the presence of SmI 2 without competitive ring opening of Newcomb's bicyclopropylic probe next to the carbonyl
Publikováno v:
Synlett. :2362-2366
In the presence of samarium diiodide and a proton donor (tert-butanol or phenol), δ-oxo-y.y-disubstituted-alkylidenemalonates readily cyclise according to the 3-exo-trig mode to give. depending on the exact nature of the substrate, trans and cis cyc
Autor:
Hélène Villar, François Guibé
Publikováno v:
Tetrahedron Letters. 43:9517-9520
In the presence of samarium diiodide and a proton source, δ-oxo-γ,γ-disubstituted-α,β-unsaturated esters readily cyclise with complete diastereocontrol to give anti-cyclopropanol products.
Publikováno v:
Synlett. 2001:0037-0040
Publikováno v:
Letters in Peptide Science. 7:187-194
The solid-phase synthesis of peptides containing Cys has been carried out using the new thiol protecting group Fsam, which is completely stable to basic and acidic conditions used in both main strategies and can be selectively removed by palladium-ca
Publikováno v:
Tetrahedron Letters. 41:3335-3338
Monoepoxides of diene-esters are regio- and stereoselectively reduced to homoallylic alcohols by dimethylamine–borane complex in the presence of acetic acid and catalytic amounts of Pd(PPh3)4.
Autor:
Carlos Afonso, Marie-George Guillerez, François Guibé, Gilles Doisneau, Hervé David, Martine Bonin
Publikováno v:
Tetrahedron Letters. 40:8557-8561
δ-Iodo- and δ-bromo-α,β-unsaturated esters with various substituents at the β- and γ-positions readily cyclise to cyclopropane compounds in the presence of samarium diiodide and a proton source.
Publikováno v:
Tetrahedron. 55:6945-6960
S-[N-[2,3,5,6-tetrafluoro-4-(N′-piperidino)-phenyl], N-allyloxycarbonyl]-aminomethyl (Fnam) derivatives of thiols in general and cysteine in particular are readily deprotected by palladium catalysed allylic cleavage in the presence of various nucle
Publikováno v:
Tetrahedron. 55:6931-6944
S-allyloxycarbonylaminomethyl derivatives of thiols in general and cysteine in particular are readily deprotected by palladium catalysed hydrostannolysis with tributyltin hydride in the presence of acetic acid. They are perfectly stable in the basic