Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Frédéric Miege"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 7, Iss 1, Pp 717-734 (2011)
Cyclopropenes as substrates entered the field of gold catalysis in 2008 and have proven to be valuable partners in a variety of gold-catalyzed reactions. The different contributions in this growing research area are summarized in this review.
Externí odkaz:
https://doaj.org/article/d56dcf4f6d1f4d4fba6027e7302e3d85
Gold-Catalyzed Rearrangement of (Silylcyclopropenyl)methyl Ethers into (Silylmethylene)cyclopropanes
Publikováno v:
SYNTHESIS
SYNTHESIS, Georg Thieme Verlag, 2016, 48 (19), pp.3165-3174. ⟨10.1055/s-0035-1561486⟩
SYNTHESIS, Georg Thieme Verlag, 2016, 48 (19), pp.3165-3174. ⟨10.1055/s-0035-1561486⟩
International audience; Methoxymethyl ethers derived from 2-(dimethylphenylsilyl)cycloprop-1-enyl carbinols undergo gold-catalyzed rearrangement leading to [(Z)-(dimethylphenylsilyl)methylene]cyclopropanes in moderate to high yields with methyl forma
Publikováno v:
Chemistry - A European Journal. 18:7810-7822
The gold(I)-catalysed cycloisomerisation of appropriately substituted 1,6-cyclopropene-enes proceeds through regioselective electrophilic ring opening of the three-membered ring to generate an alkenyl gold carbenoid that achieves the intramolecular c
Publikováno v:
Angewandte Chemie. 123:6054-6059
The methodology provides access to functionalized carbocyclic or heterocyclic scaffolds fused to an aromatic ring.
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 7, Iss 1, Pp 717-734 (2011)
Beilstein Journal of Organic Chemistry
Beilstein Journal of Organic Chemistry
Cyclopropenes as substrates entered the field of gold catalysis in 2008 and have proven to be valuable partners in a variety of gold-catalyzed reactions. The different contributions in this growing research area are summarized in this review.
Autor:
Janine Cossy, Frédéric Miege, Anne-Frédérique Salit, Marion Barbazanges, Christophe Meyer, Marie-Hélène Larraufie
Publikováno v:
Synlett. 2008:2583-2586
The synthesis ofy-alkylidene a,p-unsaturated 6-lactones was achieved by ring-closing metathesis of acrylates derived from (1,3-butadien-2-yl)methanols. The application to the synthesis of the C1-C8 subunit ofbiselide E is reported.
Publikováno v:
ChemInform. 46
ConspectusActivation of unsaturated carbon–carbon bonds by means of transition metal catalysts is an exceptionally active research field in organic synthesis. In this context, due to their high ring strain, cyclopropenes constitute an interesting c
Publikováno v:
Patai's Chemistry of Functional Groups
Cyclopropenes have often been used as substrates in transition metal-promoted or catalyzed reactions. Since the first reports in 2008, gold-catalyzed reactions of cyclopropenes have rapidly evolved to an active research field. The observed reactivity
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::218d2619fa1d1b77db03ef3beea6f2f5
https://doi.org/10.1002/9780470682531.pat0803
https://doi.org/10.1002/9780470682531.pat0803
Publikováno v:
Accounts of chemical research. 48(4)
Activation of unsaturated carbon-carbon bonds by means of transition metal catalysts is an exceptionally active research field in organic synthesis. In this context, due to their high ring strain, cyclopropenes constitute an interesting class of subs
Autor:
Barry M. Trost, Frédéric Miege
Publikováno v:
Journal of the American Chemical Society
A zinc–ProPhenol-catalyzed direct asymmetric aldol reaction between glycine Schiff bases and aldehydes is reported. The design and synthesis of new ProPhenol ligands bearing 2,5-trans-disubstituted pyrrolidines was essential for the success of this