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Influence of Pore Size on Carbon Dioxide Diffusion in Two Isoreticular Metal-Organic Frameworks

Autor: Forse, AC, Colwell, KA, Gonzalez, MI, Benders, S, Torres-Gavosto, RM, Blümich, B, Reimer, JA, Long

Publikováno v: Chemistry of Materials, vol 32, iss 8

The rapid diffusion of molecules in porous materials is critical for numerous applications including separations, energy storage, sensing, and catalysis. A common strategy for tuning guest diffusion rates is to vary the material pore size, although d

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3c512140d207dcc4fa969e6811d04ac0
https://escholarship.org/uc/item/9dn9j5mp

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Aromaticity as a Guide to Planarity in Conjugated Molecules and Polymers

Autor: Wood, BM, Forse, AC, Persson, KA

Publikováno v: The Journal of Physical Chemistry C, vol 124, iss 10
Journal of Physical Chemistry C, vol 124, iss 10

Conjugated molecules and polymers have the ability to be transformative semiconducting materials; however, to reach their full potential a detailed understanding of the factors governing the molecular structure is crucial for establishing design prin

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::047051f2bfa09b2248bf9937ef8bb852
https://escholarship.org/uc/item/0hr407z9

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Revisiting Anisotropic Diffusion of Carbon Dioxide in the Metal-Organic Framework Zn2(dobpdc)

Autor: Forse, AC, Altobelli, SA, Benders, S, Conradi, MS, Reimer, JA

Publikováno v: Forse, AC; Altobelli, SA; Benders, S; Conradi, MS; & Reimer, JA. (2018). Revisiting Anisotropic Diffusion of Carbon Dioxide in the Metal-Organic Framework Zn2(dobpdc). Journal of Physical Chemistry C, 122(27), 15344-15351. doi: 10.1021/acs.jpcc.8b02843. UC Berkeley: Retrieved from: http://www.escholarship.org/uc/item/9r15574m

© Copyright 2018 American Chemical Society. The diffusion of gases confined in nanoporous materials underpins membrane and adsorption-based gas separations, yet relatively few measurements of diffusion coefficients in the promising class of material

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=od_______325::37d1142a1f46d834dc1433a67c8a44eb
http://www.escholarship.org/uc/item/9r15574m

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NMR Spectroscopy Reveals Adsorbate Binding Sites in the Metal-Organic Framework UiO-66(Zr)

Autor: Nandy, A, Forse, AC, Witherspoon, VJ, Reimer, JA

Publikováno v: Nandy, A; Forse, AC; Witherspoon, VJ; & Reimer, JA. (2018). NMR Spectroscopy Reveals Adsorbate Binding Sites in the Metal-Organic Framework UiO-66(Zr). Journal of Physical Chemistry C, 122(15), 8295-8305. doi: 10.1021/acs.jpcc.7b12628. UC Berkeley: Retrieved from: http://www.escholarship.org/uc/item/2759b8x4
Journal of Physical Chemistry C, vol 122, iss 15

© 2018 American Chemical Society. We assign 1H and 13C NMR resonances emanating from acetone, methanol, and cyclohexane adsorbed inside the pores of UiO-66(Zr). These results are informed by density functional theory (DFT) calculations, which probe

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::96d1fcfe4f1ce666e69904b1dc1d0eb5
http://www.escholarship.org/uc/item/2759b8x4

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Unexpected Diffusion Anisotropy of Carbon Dioxide in the Metal-Organic Framework Zn2(dobpdc)

Autor: Forse, AC, Gonzalez, MI, Siegelman, RL, Witherspoon, VJ, Jawahery, S, Mercado, R, Milner, PJ, Martell, JD, Smit, B, Blümich, B, Long, JR, Reimer, JA

Publikováno v: Forse, AC; Gonzalez, MI; Siegelman, RL; Witherspoon, VJ; Jawahery, S; Mercado, R; et al.(2018). Unexpected Diffusion Anisotropy of Carbon Dioxide in the Metal-Organic Framework Zn2(dobpdc). Journal of the American Chemical Society, 140(5), 1663-1673. doi: 10.1021/jacs.7b09453. UC Berkeley: Retrieved from: http://www.escholarship.org/uc/item/3xd3z5rz

© 2018 American Chemical Society. Metal-organic frameworks are promising materials for energy-efficient gas separations, but little is known about the diffusion of adsorbates in materials featuring one-dimensional porosity at the nanoscale. An under

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=od_______325::e53e2e8e6ab8550062aa63992884f2ff
http://www.escholarship.org/uc/item/3xd3z5rz

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How Strong Is the Hydrogen Bond in Hybrid Perovskites?

Autor: Svane, KL, Forse, AC, Grey, CP, Kieslich, G, Cheetham, AK, Walsh, A, Butle, KT

Publikováno v: Journal of Physical Chemistry Letters, vol 8, iss 24

Hybrid organic–inorganic perovskites represent a special class of metal–organic framework where a molecular cation is encased in an anionic cage. The molecule–cage interaction influences phase stability, phase transformations, and the molecular

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::3dec7df21b88c726ddabd4e19b0d7b84
https://escholarship.org/uc/item/30w0r782

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Metal-Organic Nanosheets Formed via Defect-Mediated Transformation of a Hafnium Metal-Organic Framework

Autor: Cliffe, MJ, Castillo-Martínez, E, Wu, Y, Lee, J, Forse, AC, Firth, FCN, Moghadam, PZ, Fairen Jimenez, D, Gaultois, MW, Hill, JA, Magdysyuk, OV, Slater, B, Goodwin, AL, Grey, CP

We report a hafnium-containing MOF, hcp UiO-67(Hf), which is a ligand-deficient layered analogue of the face-centered cubic fcu UiO-67(Hf). hcp UiO-67 accommodates its lower ligand:metal ratio compared to fcu UiO-67 through a new structural mechanism

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::93ce92cd922e798e5e0645a62243366f
https://ora.ox.ac.uk/objects/uuid:6f35dc6f-43da-4979-a431-cff5052eb9cf

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Direct observation of ion dynamics in supercapacitor electrodes using $\textit{in situ}$ diffusion NMR spectroscopy

Autor: Forse, AC, Griffin, JM, Merlet, C, Carretero Gonzalez, J, Raji, ARO, Trease, NM, Grey, CP

Ionic transport inside porous carbon electrodes underpins the storage of energy in supercapacitors and the rate at which they can charge and discharge, yet few studies have elucidated the materials properties that influence ion dynamics. Here we use

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NMR studies of adsorption and diffusion in porous carbonaceous materials

Autor: Forse, AC, Merlet, C, Grey, CP, Griffin, JM

Porous carbonaceous materials have many important industrial applications including energy storage, water purification, and adsorption of volatile organic compounds. Most of their applications rely upon the adsorption of molecules or ions within the

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Solvent-derived defects suppress adsorption in MOF-74

Autor: Yao Fu, Yifeng Yao, Alexander C. Forse, Jianhua Li, Kenji Mochizuki, Jeffrey R. Long, Jeffrey A. Reimer, Gaël De Paëpe, Xueqian Kong

Publikováno v: Nature communications, vol 14, iss 1

Defects in metal-organic frameworks (MOFs) have great impact on their nano-scale structure and physiochemical properties. However, isolated defects are easily concealed when the frameworks are interrogated by typical characterization methods. In this

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d15966006d904d8c1f8bfe37ae63b564
https://escholarship.org/uc/item/4012t5bx

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