Synthesis and characterization of N-silylated, C1-symmetric benzamidinates of lithium, sodium, and tin(II)

Autor: Peter B. Hitchcock, Alexei V. Khvostov, Michael F. Lappert, Floria Antolini

Publikováno v: Canadian Journal of Chemistry. 84:269-276

The synthesis and characterization of complexes obtained from the reactions between Li[N-t-Bu(SiMe3)] (A) or the sodium analogue Na[N-t-Bu(SiMe3)] (B) and the cyanoarene RCN (R = Ph or 4-MeOC6H4) are discussed. These are the THF adduct [Li{µ-cis-N(t

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::447001418fa1236f3848071d630768f7
https://doi.org/10.1139/v05-250

Synthesis and Structures of Alkali Metal Amides Derived from the Ligands [N(SiMe 2 Ph)(SiMe 3 )] − , [N( t Bu)(SiMe 3 )] − , [N(Ph)(2‐C 5 H 4 N)] − , and [N(2‐C 5 H 4 N) 2 ] −

Autor: Floria Antolini, Peter B. Hitchcock, Alexei V. Khvostov, Michael F. Lappert

Publikováno v: European Journal of Inorganic Chemistry. 2003:3391-3400

The following crystalline complexes are reported: [(M{μ-N(SiMe2Ph)(SiMe3)})2]n [the cis complex for n = 1 and M = Li (1); and the trans complexes with n = ∞ and M = Na (2), K (4), Rb (5), Cs (6)], [(Na{μ-trans-N(SiMe2Ph)(SiMe3)})2(tmeda)] (3), [(

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b8c8a623d5b4daf1c1f59c338faa6206
https://doi.org/10.1002/ejic.200300283

Synthesis and Structure of an Azatrisilacyclobutane and Its Precursor, a Novel Lithium Enamide Having a Tricyclic (LiNSiO)2 Skeleton

Autor: Peter B. Hitchcock, Michael F. Lappert, Floria Antolini, Barbara Gehrhus

Publikováno v: Angewandte Chemie International Edition. 41:2568-2571

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d650b55e393779678453bec831811926
https://doi.org/10.1002/1521-3773(20020715)41:14<2568::aid-anie2568>3.0.co

Insertion Reactions of the Stable Silylene Si[N(CH2tBu)2C6H4-1,2]

Autor: Floria Antolini, Xiaoping Cai, Barbara Gehrhus, Peter B. Hitchcock, Michael F. Lappert, Massimo Parrucci, J. Chris Slootweg

Publikováno v: ChemInform. 36

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::655972eaa94ef6dad29153baac716b3c
https://doi.org/10.1002/chin.200538237

Reaction of the silylene Si[(NCH2But)2C6H4-1,2] with the alkali metal silylamides M[N(SiMe3)R](M = Li, Na or K; R = SiMe3 or SiMe2Ph)

Autor: Floria Antolini, Michael F. Lappert, Peter B. Hitchcock, Barbara Gehrhus, J. Chris Slootweg

Publikováno v: Antolini, F, Gehrhus, B, Hitchcock, P B, Lappert, M F & Slootweg, J C 2004, ' Reaction of the sylilene Si[NCH2tBu)2C6H4-1,2] with the alkali metal silylamides M[N(SiMe3)R] (M = Li, Na or K; R = SiMe3 or SiMe2Ph) ', Dalton Transactions, pp. 3050-3051 . https://doi.org/10.1039/b409594d
Dalton Transactions, 3288-3294. Royal Society of Chemistry
ISSUE=20;STARTPAGE=3288;ENDPAGE=3294;ISSN=1477-9234;TITLE=Dalton Transactions
Dalton Transactions, 3050-3051. Royal Society of Chemistry
STARTPAGE=3050;ENDPAGE=3051;ISSN=1477-9234;TITLE=Dalton Transactions
Antolini, F, Gehrhus, B, Hitchcock, P B, Lappert, M F & Slootweg, J C 2004, ' Reaction of the silylene Si[(NCH2But) 2C6H4-1,2] with the alkali metal silylamides M[N(SiMe3)R] (M = Li, Na or K; R = SiMe3 or SiMe2Ph) ', Dalton Transactions, no. 20, pp. 3288-3294 . https://doi.org/10.1039/b409594d

The thermally stable silylene Si[(NCH(2)Bu(t))(2)C(6)H(4)-1,2] 1 undergoes oxidative addition reactions with the alkali metal silylamides MN(SiMe(3))(2)(M = Li, Na or K) to afford the new alkali metal amides MN(SiMe(3))[(1)SiMe(3)][M = Li (2), Na (3)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::281778ab20ba7911cf1fc22dafebf1f5
https://pubmed.ncbi.nlm.nih.gov/15483713