Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Florence Labrize"'
Publikováno v:
Journal of Coordination Chemistry. 53:69-77
The reaction between barium 2,6-dimethylphenoxide (1) and copper 2,2,6,6-tetramethylheptane-3,5-dionate gave the volatile β-diketonatoaryloxide [Cu(μ-OC6H3-2,6-Me2)(thd)]2 (2). The complex was characterized by elemental analysis, IR and ESR spectro
Autor:
Pascal Tobaly, Florence Labrize, Sabine Halut, Jean-Claude Daran, Liliane G. Hubert-Pfalzgraf
Publikováno v:
Polyhedron. 15:2707-2718
Heterometallic complexes [YBa 2 (HFIP) 7 (THF) 3 ] ( 1 ) and [BaCu(HFIP) 4 (DME) 2 ] ( 2 ); HFIP = 1,1,1,3,3,3-hexafluoro-2-propoxide) were obtained by metathesis reactions between YCl 3 or CuCl 2 and “Ba(HFIP) 2 ” obtained in situ or by using th
Publikováno v:
Polyhedron. 15:577-589
Reactions involving Y(thd) 3 and Cu(thd) 2 with barium tert-butoxide or 2-dimethylamino-2-propoxide were investigated. The mixed-metal complexes [YBa 3 (OBu t ) 6 (thd) 3 ] ( 1 ) and [BaCu(OBu t ) 2 (thd) 2 ] m ( 3 ) (thdH = 2,2,6,6-tetramethylheptan
Publikováno v:
Polyhedron. 14:881-888
Metathesis involving YCl3 and sodium 1,1,1,3,3,3-hexafluoro-2-propoxide offered a mixed-metal species, YNa3[OCH(CF3)2]6(THF)3 (1). The reaction between 1 and yttrium and copper derivatives, β-diketonates and halides, gave access to YNa2 [OCH(CF3)2]4
Publikováno v:
Polyhedron. 13:3323-3327
The reaction between metallic barium and fluoroisopropanol or alcoholysis of [Ba(OPri)2] produces a pentanuclear fluoroalkoxide. Its X-ray structure determination showed its formulation to correspond to Ba5(μ5-OH)[μ3-OCH(CF3)2]4[μ2-OCH(CF3)2]4 [OC
Publikováno v:
Polyhedron. 13:2163-2172
The reaction between the barium derivative resulting from barium chips and 1-dimethylamino-2-propanol and 2,2,6,6-tetramethyl-3,5-heptanedione (thdH) in a 1 : 1 stoichiometry produced the β-diketonatoalkoxide derivative 2 or [Ba(thd)2(OHCH MeCH2NMe2
Publikováno v:
J. Chem. Soc., Chem. Commun.. :1556-1558
The volatile compound, Y2Ba[OCH(CF3)2]4(thd)4, is obtained by treating a mixed-metal yttrium–barium hexafluoroisopropoxide derivative and yttrium tetramethylheptanedionate Y(thd)3; its structure is based on a central Ba[OCH(CF3)2]42– moiety conne
Publikováno v:
MRS Proceedings. 346
The fluoroisopropoxide ligand (HFIP) has allowed the synthesis of mixed-metal homoleptic Ba2Y and CuBa alkoxides. However, although these species are all volatile, their poor thermal stability precludes their use as CVD precursors. Their properties h
Conference
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