Investigations into the reactivity of lithium indenyl with alpha diimines with chlorinated backbones and formation of related functional ligands and metal complexes

Autor: Sofia I. Pascu, Mark E. Fischer, Chi Tien Chen, Ino C. Vei, Caroline Windsor, David G. Calatayud, Malcolm L. H. Green

Publikováno v: Chen, C T, Fischer, M E, Windsor, C, Vei, I C, Calatayud, D G, Green, M L H & Pascu, S I 2016, ' Investigations into the reactivity of lithium indenyl with alpha diimines with chlorinated backbones and formation of related functional ligands and metal complexes ', Polyhedron, vol. 119, pp. 532-547 . https://doi.org/10.1016/j.poly.2016.09.021

Reaction between lithium indenyl and a chlorine substituted alpha diimine of the form [{Cl(NPh)2}C)]2 unexpectedly yielded the corresponding NH rearranged derivative [PhN(H)C(C9H6)]2 (1) rather than the predicted symmetrical α-diimine. This compound

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https://doi.org/10.1016/j.poly.2016.09.021