Výsledky vyhledávání - "Fiona L.B. Bathie"

Dissecting transmetalation reactions at the molecular level: C-B versus F-B bond activation in phenyltrifluoroborate silver complexes

Autor: Allan J. Canty, Richard A. J. O'Hair, Adam W. E. Stewart, Fiona L.B. Bathie

Publikováno v: Dalton transactions (Cambridge, England : 2003). 50(4)

The gas-phase unimolecular reactions of the silver(I) complex [Ag(PhBF3)2]−, formed via electrospray ionisation mass spectrometry of solutions containing the phenyltrifluoroborate salt and AgNO3, are examined. Upon collision induced dissociation (C

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::19c2ae33d56bdb099dd663c4bc95a5dc
https://pubmed.ncbi.nlm.nih.gov/33439189

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Unimolecular reactivity of organotrifluoroborate anions, RBF 3 − , and their alkali metal cluster ions, M(RBF 3 ) 2 − (M = Na, K; R = CH 3 , CH 3 CH 2 , CH 3 (CH 2 ) 3 , CH 3 (CH 2 ) 5 , c‐C 3 H 5 , C 6 H 5 , C 6 H 5 CH 2 , CH 2 CHCH 2 , CH 2 CH, C 6 H 5 CO)

Autor: Chris J. Bowen, Fiona L.B. Bathie, Craig A. Hutton, Richard A. J. O'Hair

Publikováno v: Rapid Communications in Mass Spectrometry. 32:1045-1052

RATIONALE Potassium organotrifluoroborates (RBF3 K) are important reagents used in organic synthesis. Although mass spectrometry is commonly used to confirm their molecular formulae, the gas-phase fragmentation reactions of organotrifluoroborates and

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::bb2e50cf0fede016b8f9d159bd8cf0b6
https://doi.org/10.1002/rcm.8134

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