Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Fga Stone"'
Publikováno v:
Inorganic Chemistry. 47:713-722
Ultraviolet irradiation of [PPh(4)][closo-1-CB(8)H(9)] with [Re(2)(CO)(10)] in THF (tetrahydrofuran) at ambient temperature affords the dirhenacarborane anion [6,10-{Re(CO)(4)}-10-(micro-H)-6,6,6-(CO)(3)-closo-6,1-ReCB(8)H(8)]-, isolated as its [PPh(
Publikováno v:
Inorganic Chemistry. 38:2981-2988
In ethanol the charge-compensated molecule exo-nido-ruthenacarborane [5,6,10-{RuCl(PPh(3))(2)}-5,6,10-mgr;-(H)(3)-10-H-7,8-C(2)B(9)H(8)] reacts with KOH to afford the anionic closo-complex [RuH(PPh(3))(2)(eta(5)-7,8-C(2)B(9)H(11))](-) isolated as its
Publikováno v:
Organometallics. 17:2258-2270
The rhenium salt [N(PPh3)2]2[Re(CO)3(η5-7-CB10H11)] (1a) reacts with the group 9 transition-metal complexes [M(NCMe)3(η5-C5Me5)][BF4]2 (M = Rh, Ir) to form neutral binuclear metal compounds [ReM(CO...
Publikováno v:
Organometallics. 17:1402-1411
The salts [X]2[Re(CO)3(η5-7-CB10H11)] (X = N(PPh3)2 (2a), X = NEt3(CH2Ph) (2b)) have been synthesized from the reaction between [Na]3[nido-7-CB10H11] and [ReBr(THF)2(CO)3] (THF = tetrahydrofuran) followed by addition of XCl. An X-ray diffraction stu
Publikováno v:
Inorganic Chemistry. 35:2967-2976
The compounds [RhX(PPh3)3] react with nido-7-NH2But-7-CB10H12 in toluene to give the 16-electron complexes [RhX(PPh3)(η5-7-NH2But-7-CB10H10)] (1a, X = Br; 1b, X = Cl). The structure of the zwitteri...
Autor:
J. C. Jeffery, Paul A. Jelliss, Eric L. Sappenfield, Donald F. Mullica, Hendershot Sl, Fga Stone
Publikováno v:
Inorganic Chemistry. 35:6561-6570
The compounds [Co2(CO)8] and nido-7,8-C2B9H13 react in CH2Cl2 to give a complex mixture of products consisting primarily of two isomers of the dicobalt species [Co2(CO)2(η5-7,8-C2B9H11)2] (1), together with small amounts of a mononuclear cobalt comp
Publikováno v:
Inorganic Chemistry. 35:5399-5402
The electronically unsaturated complexes [RhX(PPh3)(η5-7-NH2But-7-CB10H10)] (X = Br, Cl) react with 1 mol equiv of the diazo compound N2C(H)CO2Et in CH2Cl2 at room temperature to give the species [RhX(PPh3)(η5-7-NH2But-8-CH2CO2Et-7-CB10H9)] resulti
Publikováno v:
Inorganic Chemistry. 33:4927-4933
Treatment of [Pd2@-C1)2(q3-C3Hs)~] with Naz[nido-7,8-Me2-7,8-C2B9H9] in thf (tetrahydrofuran), followed by addition of [NEit]Cl, gives the complex [NEk][Pd(q3-C3Hs)(q5-7,8-Me2-7,8-C2B9H9)] (IC). Protonation of CH2Cl2 solutions of this species with HB
Publikováno v:
Inorganic Chemistry. 32:3943-3947
Reactions between the reagents [NEt 4 ] [10-endo-{Au(PPh 3 )}-7,8-R' 2 -nido-7,8-C 2 B 9 H 9 ] (1, R'=Me or H) and compounds [PtCl(R)L 2 ] (R=H, L=PEt 3 ; R=Me, L=PMe 2 Ph) in CH 2 Cl 2 at room temperature afford the platinum-gold complexes [10-exo-{
Autor:
Jason A. Kautz, Shaowu Du, Riis-Johannessen T, Fga Stone, Thomas D. McGrath, Miller Ta, Xiu Lian Lu, J. C. Jeffery
Publikováno v:
Inorganic chemistry. 44(8)
The manganacarborane dianion in [N(PPh(3))(2)][NEt(4)][1,1,1-(CO)(3)-2-Ph-closo-1,2-MnCB(9)H(9)] (1b) reacts with cationic transition metal-ligand fragments to give products in which the electrophilic metal groups (M') are exo-polyhedrally attached t