Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Fernanda Cimadevilla"'
Autor:
Daniel García-Vivó, Antonio Tiripicchio, M. Esther García, Fernanda Cimadevilla, Miguel A. Ruiz, Claudia Graiff
Publikováno v:
Organometallics. 32:4624-4635
The hydroxycarbyne complex salt [W2Cp2(μ-COH)(μ-PPh2)2]BF4 (1) reacted rapidly with water in the presence of the oxidant [FeCp2]BF4 to give the hydroxo complex salt [W2Cp2(OH)(μ-PPh2)2(CO)]BF4, a p...
Autor:
M. Esther García, Antonio Tiripicchio, Miguel A. Ruiz, Daniel García-Vivó, Claudia Graiff, Fernanda Cimadevilla
Publikováno v:
Inorganic Chemistry. 51:10427-10436
The title compound reacted with CO at room temperature in the presence of excess HBF(4)·OEt(2) to yield a mixture of the electron-precise complexes [W(2)Cp(2)(μ-PPh(2))(2)(CO)(4)](BF(4))(2) and [W(2)Cp(2)(μ-PPh(2))(2)(CO)(3)(OH(2))](BF(4))(2), wit
Autor:
M. Teresa Rueda, Sabine Halut, Daniel García-Vivó, Fernanda Cimadevilla, M. Esther García, Miguel A. Ruiz
Publikováno v:
Journal of Organometallic Chemistry. 699:67-74
The dimolybdenum complex cis -[Mo 2 Cp 2 (O)(μ-PPh 2 ) 2 (CO)] ( 1 ) reacted with either [H(OEt 2 ) 2 ](BAr′ 4 ), (Ar′ = 3,5-C 6 H 3 (CF 3 ) 2 ), or HBF 4 ·OEt 2 to give the corresponding hydroxo derivatives [Mo 2 Cp 2 (OH)(μ-PPh 2 ) 2 (CO)] +
Autor:
M. Esther García, Claudia Graiff, Miguel A. Ruiz, Fernanda Cimadevilla, Daniel García-Vivó, Antonio Tiripicchio
Publikováno v:
Inorganic chemistry. 51(13)
The title compound reacted rapidly with CN(t)Bu at room temperature by displacing the BF(4)(-) ligand and incorporating three molecules of isocyanide to yield the electron-precise complex [Mo(2)Cp(2)(μ-PPh(2))(2)(CN(t)Bu)(3)(CO)](BF(4))(2), which wa