Zobrazeno 1 - 10
of 47
pro vyhledávání: '"Fernand Dejehet"'
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 80:481-499
On a determine les facteurs G de transformation de la dithizone, en solution dans des solvants organiques, par irradiation aux σ du 60Co. Dans le chloroforme, aux concentrations de 10−5, 2.10−5 et 10−4 mol.l−1 on trouve respectivement G(–d
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 99:535-541
Modifications in the synthesis procedure of calcite involve statistically significant changes in the relative intensities of the EPR lines of the irradiated samples. Of the 6 (or 8) paramagnetic centres produced by γ- (or α-) irradiations, four are
Publikováno v:
Applied Radiation and Isotopes. 52:1327-1336
Enamel from 6 different positions in a well preserved elephant tooth from the Karlich-Seeufer site in Germany has been irradiated up to 32 kGy. The X-band (v = 9.5 GHz) ESR spectra of two subsamples have been decomposed into three real components wit
Publikováno v:
Journal de Chimie Physique et de Physico-Chimie Biologique. 96:741-753
Calcium carbonate monohydrate spherulites (similar to 10(2) mu m diameter) with different magnesium contents were synthesized from artificial seawater, Stable spherulites are only obtained if [Mg]/[Ca] greater than or equal to 1 - 1.3 in the mother s
Autor:
Harold M. Swartz, Henryk Taper, Bernard Gallez, René Debuyst, Fuminori Goda, Roger Demeure, Tadeusz Walczak, Ke Jian Liu, Fernand Dejehet
Publikováno v:
Magnetic Resonance in Medicine. 40:152-159
The development of oxygen-sensitive paramagnetic materials is being pursued actively because of their potential applications in in vivo EPR oximetry. Among these materials, several charcoals and carbohydrate chars are of special interest because of t
Autor:
J L De Keyser, Pierre Dumont, Bernard Gallez, René Debuyst, Roger Demeure, V. Lacour, Fernand Dejehet
Publikováno v:
Magnetic Resonance Materials in Physics, Biology and Medicine. 2:61-68
Synthetic methods are described leading to polysubstituted spin labeled polysaccharides (dextran 70, 110, 200, and arabinogalactan), which are potential contrast agents in magnetic resonance imaging. The nitroxyl moieties bound to a polysaccharide yi
Autor:
Pierre Dumont, Roger Demeure, Fernand Dejehet, Bernard Gallez, J L De Keyser, René Debuyst, V. Lacour
Publikováno v:
Magnetic Resonance Imaging. 12:61-69
In this study, we report the synthesis and the evaluation as MRI contrast agent of arabinogalactan/pyrrolidinoxyl radicals (PCA) covalent adduct (SLAG:Spin Labelled ArabinoGalactan). Arabinogalactan was used as targeting device, as it is recognized b
Autor:
Cécile Grandin, Bernard E. Van Beers, Bernard Gallez, Fernand Dejehet, Jacques Pringot, Henryk Taper, Roger Demeure, René Debuyst, Pierre Dumont
Publikováno v:
Magnetic Resonance in Medicine. 30:592-599
In this study, we report the synthesis and the evaluation as MRI contrast agent of a new compound (nitroxyl fatty acid, NFA), where a pyrrolidinoxyl radical (3-carboxy-proxyl, PCA) is linked to a fatty acid moiety. Fatty acids were selected as vector
Publikováno v:
Applied Radiation and Isotopes. 44:293-297
When spherulitic grains of (CaCO3.H2O)-C-12, C-13 are gamma-irradiated at room temperature, only three isotropic paramagnetic species are produced: 1) the tumbling CO3- radical with g = 2.0115 and A13c = 11.4 gauss; 2) the tumbling CO2- radical with
Publikováno v:
Toxicology Letters. 63:35-45
Three piperidinoxyl radicals were found to be directly mutagenic in Salmonella typhimurium TA 100, one pyrrolidinoxyl compound had weaker activity, and two other pyrrolidinoxyl derivatives did not produce an increase of the spontaneous revertants. Th