Electronic Properties, Redox Behavior, and Interactions with H2O2 of pH-Sensitive Hydroxyphenyl-1,2,4-triazole-Based Oxovanadium(V) Complexes

Autor: Browne, WR, Ligtenbarg, AGJ, de Boer, JW, van den Berg, TA, Lutz, M, Spek, AL, Hartl, F, Hage, R, Feringa, BL, Spek, Anthony L., Feringa, Bernard

Publikováno v: Inorganic Chemistry, 45(7), 2903-2916. AMER CHEMICAL SOC
Inorganic Chemistry, 45(7), 2903-2916. American Chemical Society
Inorganic Chemistry, 45, 2903. American Chemical Society

The syntheses and spectroscopic characterization of two 1,2,4-triazole-based oxovanadium(V) complexes are reported: 1(-)[VO(2)L1](-) and 2 [(VOL2)(2)(OMe)(2)] (where H(2)L1 = 3-(2'-hydroxyphenyl)-5-(pyridin-2"-yl)-H-1-1,2,4-triazole, H3L2 = bis-3,5-(

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4c8471606b597bbd4b6471ab912d9914
https://hdl.handle.net/11245/1.257065

A catalytic route to acyclic chiral building blocks: Applications of the catalytic asymmetric conjugate addition of organozinc reagents to cyclic enones

Autor: Jagt, RBC, Imbos, R, Naasz, R, Minnaard, AJ, Feringa, BL

Publikováno v: Israel Journal of Chemistry, 41(4), 221-229. WILEY-V C H VERLAG GMBH

Through the Cu-phosphoramidite-catalyzed asymmetric conjugate addition a number of chiral cyclic enones are available with high ee. Here we report the sequential conjugate addition to these enones as a route towards multisubstituted chiral cyclic ket

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::19aa5fc04a8025dfc02e9f4d71f4e212
https://doi.org/10.1560/nhk0-c8je-27g9-nub3

Oxidative electrochemical switching in dithienylcyclopentenes, part 2: Effect of substitution and asymmetry on the efficiency and direction of molecular switching and redox stability

Autor: Browne, WR, de Jong, JJD, Kudernac, T, Walko, M, Lucas, LN, Uchida, K, van Esch, JH, Feringa, BL, Lucas, Linda N.

Publikováno v: Chemistry, 11(21), 6430-6441. Wiley-VCH Verlag GmbH & Co. KGaA

The electrochemical and spectroelectrochernical properties of a series of C5-substituted dithienylhexahydro- and dithienylhexafluorocyclopentenes are reported. The effect of substitution at C5 of the thienyl moiety on the redox properties is quite dr

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d1f8ffadaeb2657739777946cae15bb0
https://research.rug.nl/en/publications/9f994c45-ee37-4d12-a3ed-cf54cc4aacc3

Unidirectional molecular motor on a gold surface

Autor: van Delden, RA, ter Wiel, MKJ, Pollard, MM, Vicario, J, Koumura, N, Feringa, BL, Delden, Richard A. van

Publikováno v: Nature, 437(7063), 1337-1340. Nature Publishing Group

Molecules capable of mimicking the function of a wide range of mechanical devices have been fabricated, with motors that can induce mechanical movement attracting particular attention(1,2). Such molecular motors convert light or chemical energy into

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b63db5bb19384ed71d09d24f155b8320
https://pubmed.ncbi.nlm.nih.gov/16251960

cis-Dihydroxylation and epoxidation of alkenes by [Mn2O(RCO2)(2)(tmtacn)(2)]: Tailoring the selectivity of a highly H2O2-efficient catalyst

Autor: de Boer, JW, Brinksma, J, Browne, WR, Meetsma, A, Alsters, PL, Hage, R, Feringa, BL, Alsters, Paul L.

Publikováno v: Journal of the American Chemical Society, 127(22), 7990-7991. AMER CHEMICAL SOC

The carboxylic acid promoted cis-dihydroxylation and epoxidation of alkenes catalyzed by [MnIV2O3(tmtacn)2]2+ 1 employing H2O2 as oxidant is described. The use of carboxylic acids at cocatalytic levels not only is effective in suppressing the inheren

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5cd3548549c64b9e7736b1fc6326deaa
https://research.rug.nl/en/publications/a17247cd-fb3a-40d1-9094-59540dabc6a7