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pro vyhledávání: '"Felix Scheidt"'
Autor:
Felix Scheidt, Christian Thiehoff, Gülay Yilmaz, Stephanie Meyer, Constantin G. Daniliuc, Gerald Kehr, Ryan Gilmour
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 14, Iss 1, Pp 1021-1027 (2018)
Herein, we describe a catalytic fluorooxygenation of readily accessible N-allylcarboxamides via an I(I)/I(III) manifold to generate 2-oxazolines containing a fluoromethyl group. Catalysis is conditional on the oxidation competence of Selectfluor®, w
Externí odkaz:
https://doaj.org/article/8f44c7183a2d4562a88dc1f4f05c2339
Autor:
Constantin G. Daniliuc, Felix Scheidt, Ryan Gilmour, Stephanie Meyer, Christian Thiehoff, Gülay Yilmaz, Gerald Kehr
Publikováno v:
Beilstein Journal of Organic Chemistry
Beilstein Journal of Organic Chemistry, Vol 14, Iss 1, Pp 1021-1027 (2018)
Beilstein Journal of Organic Chemistry, Vol 14, Iss 1, Pp 1021-1027 (2018)
Herein, we describe a catalytic fluorooxygenation of readily accessible N-allylcarboxamides via an I(I)/I(III) manifold to generate 2-oxazolines containing a fluoromethyl group. Catalysis is conditional on the oxidation competence of Selectfluor®, w
Autor:
Dmytro Dudenko, Mareike C. Holland, Philipp Selter, Michael Ryan Hansen, Ryan Gilmour, Christian Mück-Lichtenfeld, Felix Scheidt, Nico Santschi, Constantin G. Daniliuc
Publikováno v:
Chemistry - A European Journal. 23:6142-6149
Pervasive in Nature, the propane unit is an essential component of numerous bioactive molecules. These range from acyclic systems, such as the neurotransmitter gamma-aminobutyric acid, through to the bicyclic nuclei of various chromanes and dihydrobe
Publikováno v:
Organic letters. 20(24)
A geminal difluorination of alkenes based on I(I)/I(III) catalysis is disclosed, which is compatible with a range of electronically and substitutionally diverse styrenes (27 examples, up to 89% yield). Employing inexpensive p-TolI as the organocataly
Autor:
Gerald Kehr, Jinjun Ren, Constantin G. Daniliuc, Timothy H. Warren, René Liedtke, Hellmut Eckert, Gerhard Erker, Allan Jay P. Cardenas, Stefan Grimme, Birgitta Schirmer, Felix Scheidt
Publikováno v:
Journal of the American Chemical Society. 136:9014-9027
The vicinal frustrated Lewis pair (FLP) mes2P-CH2CH2-B(C6F5)2 (3) reacts with phenyl(trimethylsilyl)acetylene by 1,1-carboboration to give the extended C3-bridged FLP 6 featuring a substituted vinylborane subunit. The FLP 6 actively cleaves dihydroge