Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Felix S. Geitner"'
Publikováno v:
Molecules, Vol 22, Iss 7, p 1204 (2017)
We report on the synthesis of novel coinage metal NHC (N-heterocyclic carbene) compounds of the germanium-rich metalloid clusters [Ge9R3]− and [Ge9RI2]2− with R = Si(iPr)3 and RI = Si(TMS)3. NHCDippCu{η3Ge9R3} with R = Si(iPr)3 (1) represents a
Externí odkaz:
https://doaj.org/article/d48b554e43f949fc9f254eaaeca1b2a1
Autor:
Christoph Wallach, Yasmin Selic, Felix S. Geitner, Ajeet Kumar, Erling Thyrhaug, Jürgen Hauer, Antti J. Karttunen, Thomas Friedrich Fässler
Publikováno v:
Angewandte Chemie.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b40a99aac708766bb71b12f3e17dc1b8
https://doi.org/10.1002/ange.202304088
https://doi.org/10.1002/ange.202304088
Publikováno v:
Chemical Science
Even though homoatomic nine-atom germanium clusters are known for two decades, their chemical properties are still rarely investigated. We now discovered that Zintl ion main group-element clusters possess a reactive lone pair of electrons, and we sho
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cbd8c5dd05f44bd63deda70ad9247473
https://doi.org/10.1039/d1sc00811k
https://doi.org/10.1039/d1sc00811k
Autor:
Thomas F. Fässler, Felix S. Geitner
Publikováno v:
Inorganic Chemistry. 59:15218-15227
Deltahedral nine-atom tetrel element Zintl clusters are promising building blocks for the straightforward solution-based synthesis of intermetalloid clusters through the reaction with organometallic compounds. Herein we report on novel coordination s
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a464e2d525a96afbecccbf9e65fb8644
https://doi.org/10.1021/acs.inorgchem.0c02190
https://doi.org/10.1021/acs.inorgchem.0c02190
Publikováno v:
Inorganic Chemistry. 58:13293-13298
Anionic clusters with a homoatomic [Ge9] core are species with Ge atoms in low oxidation states. In this study their reaction with early-transition-metal complexes was investigated. We report the s...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1f73004d134bea305ef94ddd980dee54
https://doi.org/10.1021/acs.inorgchem.9b02158
https://doi.org/10.1021/acs.inorgchem.9b02158
Publikováno v:
Chemistry – A European Journal. 25:12349-12356
The synthetic approach towards molecules that contain Ge atoms with oxidation state 0, and which are exclusively connected to other Ge atoms, is explored by using anionic clusters extracted from binary solids. Besides providing a novel variable metho
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5d58d28fa08d1828146a0d65ea94b97b
https://doi.org/10.1002/chem.201901673
https://doi.org/10.1002/chem.201901673
Autor:
Felix S, Geitner, Thomas F, Fässler
Publikováno v:
Inorganic chemistry. 59(20)
Deltahedral nine-atom tetrel element Zintl clusters are promising building blocks for the straightforward solution-based synthesis of intermetalloid clusters through the reaction with organometallic compounds. Herein we report on novel coordination s
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::97551bc483371716fddb706bbd705880
https://pubmed.ncbi.nlm.nih.gov/33017536
https://pubmed.ncbi.nlm.nih.gov/33017536
Publikováno v:
Angewandte Chemie (International Ed. in English)
The unique three‐dimensional structure of spherical, homoatomic nine‐atom germanium clusters opens various possibilities for the spatial arrangement of functional groups. Ligands comprising lone pairs have recently been introduced in the cluster
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::d2284e2896bf2eb515ab33a7179949ad
https://pubmed.ncbi.nlm.nih.gov/33090635
https://pubmed.ncbi.nlm.nih.gov/33090635
Publikováno v:
Angewandte Chemie. 130:14717-14721
Herein we report on the synthesis of the first multiple phosphine-substituted nonagermanide clusters in a one-step reaction from K4 Ge9 . Their reactions towards various transition metal complexes show a large variety of reactive sites. The novel thr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6f279d991f9c6c494940da90e573f983
https://doi.org/10.1002/ange.201803476
https://doi.org/10.1002/ange.201803476
Publikováno v:
Chemistry - A European Journal. 24:4103-4110
The reaction of [(Ge9 {Si(TMS)3 }2 PtBu2 )]- with NHCMes CuCl yields [(Ge9 {Si(TMS)3 }2 )(tBu2 P)]Cu(NHCMes ) (1), which is a new derivative of the recently reported monomeric zwitterionic tetrel cluster compounds [(Ge9 {Si(TMS)3 }2 )(tBu2 P)]M(NHCDi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8bf76a666021ae609573d5dd0f9b3e9f
https://doi.org/10.1002/chem.201705678
https://doi.org/10.1002/chem.201705678