Výsledky vyhledávání - "Felix M. Mück"

Homoleptic Two‐Coordinate 14‐Electron Palladium and Platinum Complexes with Two Bis(guanidinato)silylene Ligands

Autor: Johannes A. Baus, Reinhold Tacke, Rüdiger Bertermann, Felix M. Mück

Publikováno v: European Journal of Inorganic Chemistry. 2016:4867-4871

The homoleptic transition-metal bis(silylene) complexes [{{iPrNC(NiPr2)NiPr}2Si}2M] (7: M = Pd; 8: M = Pt) were synthesized by treatment of [PdCl2(SMe2)2] and [PtCl2(PiPr3)2], respectively, with the bis(guanidinato)silylene [iPrNC(NiPr2)NiPr]2Si (2).

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0d1713034fc77ec3f7da1cc462c9b370
https://doi.org/10.1002/ejic.201600872

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Lewis Acid/Base Reactions of the Bis(amidinato)silylene [iPrNC(Ph)NiPr]2Si and Bis(guanidinato)silylene [iPrNC(NiPr2)NiPr]2Si with ElPh3 (El = B, Al)

Autor: Rüdiger Bertermann, Johannes A. Baus, Reinhold Tacke, Felix M. Mück, Christian Burschka

Publikováno v: Organometallics. 35:2583-2588

The bis(amidinato)silylene [iPrNC(Ph)NiPr]2Si and the analogous bis(guanidinato)silylene [iPrNC(NiPr2)NiPr]2Si react with the Lewis acids BPh3 and AlPh3 to form the respective Lewis acid/base adducts 4–7 (adduct 4 has already been described). Compo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2620ab5355022d3a6b2e7df542772b16
https://doi.org/10.1021/acs.organomet.6b00204

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SO 2 Activation by the Bis(guanidinato)silylene [ i PrNC(N i Pr 2 )N i Pr] 2 Si: Formation of Neutral Six‐Coordinate Silicon(IV) Complexes with a Chelating Sulfito or Dithionito Ligand

Autor: Rüdiger Bertermann, Reinhold Tacke, Johannes A. Baus, Felix M. Mück

Publikováno v: European Journal of Inorganic Chemistry. 2016:3240-3245

Activation of SO2 by the donor-stabilized bis(guanidinato)silylene [iPrNC(NiPr2)NiPr]2Si (7) leads to the six-coordinate sulfitosilicon(IV) complex 12 (obtained by treatment of 7 with 1.5 molar equivalents of SO2 in n-hexane) or the six-coordinate di

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f1057dd63c2d8e6190103b7a78a59f08
https://doi.org/10.1002/ejic.201600294

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Four‐, Five‐, and Six‐Coordinate Silicon(IV) Complexes: Reactivity of the Donor‐Stabilized Silylenes [ i PrNC(Ph)N i Pr] 2 Si and [ i PrNC(N i Pr 2 )N i Pr] 2 Si Towards Me 3 SiN 3 and PhSCH 2 N 3

Autor: Rüdiger Bertermann, Johannes A. Baus, Reinhold Tacke, Felix M. Mück, Marco Nutz, Bettina Förster, Christian Burschka

Publikováno v: European Journal of Inorganic Chemistry. 2016:3246-3252

Bis(amidinato)silylene 1 and the analogous bis(guanidinato)silylene 2 reacted with Me3SiN3 to form compounds 3 [a five-coordinate silicon(IV) complex with an Si=N double bond] and 4 [a four-coordinate silicon(IV) complex with an Si=N double bond], re

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::4f00a5fc01525ba1d78eb58875e6ffba
https://doi.org/10.1002/ejic.201600402

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Reactivity of the Donor‐Stabilized Guanidinatosilylene [ArNC(NMe 2 )NAr]Si[N(SiMe 3 ) 2 ] (Ar = 2,6‐Diisopropylphenyl)

Autor: Reinhold Tacke, Christian Burschka, Johannes A. Baus, Felix M. Mück, Anna Ulmer

Publikováno v: European Journal of Inorganic Chemistry. 2016:1660-1670

To get more information about the reactivity profile of the donor-stabilized guanidinatosilylene [ArNC(NMe2)NAr]Si[N(SiMe3)2] (1; Ar = 2,6-diisopropylphenyl), a series of test reactions was studied. Thus, treatment of 1 with Me3SiN3, (PhO)2P(O)N3, Ph

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::27dcb29b676fae8aeaa136a718230524
https://doi.org/10.1002/ejic.201600099

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Reactivity of the Donor‐Stabilized Silylenes [ i PrNC(Ph)N i Pr] 2 Si and [ i PrNC(N i Pr 2 )N i Pr] 2 Si: Activation of CO 2 and CS 2

Autor: Marco Nutz, Jordi Poater, F. Matthias Bickelhaupt, Reinhold Tacke, Christian Burschka, Johannes A. Baus, Felix M. Mück

Publikováno v: Chemistry – A European Journal. 21:16665-16672

Activation of CO2 by the bis(amidinato)silylene 1 and the analogous bis(guanidinato)silylene 2 leads to the structurally analogous six-coordinate silicon(IV) complexes 4 (previous work) and 8, respectively, the first silicon compounds with a chelatin

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d73b3266acfa377a959f52e9d5eca1b7
https://doi.org/10.1002/chem.201501788

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Bi- and trimetallic rare-earth–palladium complexes ligated by phosphinoamides

Autor: Franziska Völcker, Karin Fink, Konstantinos D. Vogiatzis, Peter W. Roesky, Felix M. Mück

Publikováno v: Chemical Communications. 51:11761-11764

The synthesis of the heterometallic early-late 4d/4f bi- and trinuclear phosphinoamido Ln-Pd(0) complexes [(Ph2PNHPh)Pd{μ-(Ph2PNPh)}3Ln(μ-Cl)Li(THF)3] (Ln = Y, Lu) and [Li(THF)4][{(Ph2PNHPh)Pd}2{μ-(Ph2PNPh)}4Ln] (Ln = Y, Lu) is described. The latt

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::145eb85be1a2d17bea2eb12c3d772d85
https://doi.org/10.1039/c5cc03944d

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