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A dinuclear diamagnetic copper(II) complex, [Cu2(ophen)2]Cl2 (Hophen = 2-hydroxy-1,10-phenanthroline), has been synthesized and characterized, providing good structural evidence for the long-debated Gillard mechanism.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0cef37c9cc3f299362be9f144ecd8a36
https://hdl.handle.net/11587/327986
https://hdl.handle.net/11587/327986
Publikováno v:
Acta Crystallographica Section E: Structure Reports
In the crystal structure of the title compound, [Co(C(13)H(9)N(2)O)(2)]·2C(3)H(7)NO, the Co(II) ion is four-coordinated by two N atoms and two O atoms from two deprotonated 2-(1H-benzimidazol-2-yl)phenol ligands in a distorted tetra-hedral geometry.