Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Fedor Valach"'
Publikováno v:
Inorganica Chimica Acta. 479:106-112
The crystal structure of [Cu2(CH3BrCHCOO)4]n (I) is composed of polymeric chains. Within each chain the shortest Cu⋯Cu distances are 2.583(6) A long. The structure of [Cu2(CH2BrCH2COO)4(H2O)2] (II) is composed of asymmetric complex units mutually c
Publikováno v:
Journal of Coordination Chemistry. 63:1645-1651
[Di(acetato)bis(4-aminopyridine)aquacopper(II)] exists in two different monoclinic forms. The crystal structure of Form 1, which crystallizes in space group P21/c, was determined by X-ray crystallography. Experimental data was then compared with that
Publikováno v:
Journal of Coordination Chemistry. 62:225-233
The crystal and molecular structure of monoclinic [di(caffeine)tetrakis(2-bromopropionato)dicopper(II)] · 0.8 water was determined using direct methods and Fourier techniques. The complex crystallizes in space group C2/c and is dimeric with square p
Publikováno v:
Journal of Chemical Crystallography. 36:571-580
Based on the bond-valence sum model the continual transition between the bidentate and monodentate bonding mode of carboxylato group and minimum of Cu–O bond lengths were estimated. The dependence of Cu⋯Cu separation on Cu–N bond length in binu
This book introduces the concept of crystallographic non- rigidity and asymmetry of the transition elements as central atoms organometallic compounds. This intrinsic behavior of central atoms in condensed matter is quantified by applying statistical
Autor:
Milan Mazúr, Fedor Valach, Milan Melnik, Jozef Švorec, Ján Moncol, Miroslava Valková, Marian Valko, Christina J. Williams, Harry Morris
Publikováno v:
Journal of Molecular Structure. 659:53-60
The X-band Electron Spin Resonance spectra, ESR, of Cu(II) complexes with the carboxylic acids, HCOOH, CH3COOH, ClCH2COOH, Cl2CHCOOH, Cl3CCOOH, F2ClCOOH, CH3CH2COOH, niflumic acid and the ligands nicotinamide and papaverine have been studied. The com
Publikováno v:
Polyhedron. 20:1933-1937
The crystal and molecular structure of tetrakis(μ-o-propionato)bis(methyl 3-pyridyl-N-carbamate)dicopper(II) at 190 K was determined by X-ray analysis. The internuclear Cu⋯Cu distance is 2.6395(3) A. CuO bond lengths are 1.961(1), 1.9678(9), 1.
Publikováno v:
Zeitschrift für Kristallographie - Crystalline Materials. 215:56-60
The crystal and molecular structure of tetrakis(2-fluorobenzoato-O,O´)-bis(2-fluorobenzoate-O) dicopper(II) - C42H26Cu2F60O12 - has been determined at room temperature. The blue-green crystals are monoclinic, space group P21/n (No.14), with unit cel
Autor:
Fedor Valach
Publikováno v:
Polyhedron. 18:699-706
Bond valence as the function of inter-nuclear distance for Cu–O and Cu–N bonds were estimated. Based on the developed bond-valence theory a mutual dependence between the bond length in copper coordination sphere with chromophores CuO 6 , CuO 5 ,
Publikováno v:
Polyhedron. 16:1461-1464
The crystal and molecular structure of the first copper(II) complex of (2-{[3-trifluoromethyl) phenyl]amino}-3-pyridinecarboxylate with 3-pyridylmethanol as neutral ligand was determined by X-ray analysis.