Zobrazeno 1 - 10
of 43
pro vyhledávání: '"Fe2(Co)6(Mu-Se2)"'
Publikováno v:
Journal of Organometallic Chemistry. 694:3043-3045
Photolysis of a hexane solution containing Fe(CO)(5) and CS(2) leads to desulfurization and formation of a novel cluster [{Fe(2)(CO)(6)}(2)(mu-C(2)S(3))] (1). Its molecular structure was determined by single crystal X-ray diffraction methods and show
Autor:
Arnold L. Rheingold, Bala Manimaran, Glenn P. A. Yap, Pradeep Mathur, Md. Munkir Hossain, Louise M. Liable-Sands
Publikováno v:
Journal of Organometallic Chemistry. 540:165-168
The tris-methylene bridged compound (NO)(4)Fe2Se(mu-CH2)(3) has been isolated. It has been characterised by IR and H-1, C-13, and Se-77 NMR spectroscopy. Its structure has been determined by single-crystal X-ray diffraction methods. The structure con
Publikováno v:
Journal of Organometallic Chemistry. 491:291-294
The synthesis and crystal structure of (CO) 6 Fe 2 (μ-SeMe) 2 (1) is reported. The dianion [Fe 2 (CO) 6 (μ-SeMe) 2 ] 2− , obtained by the reaction of Fe 2 (CO) 6 (η-Se 2 ) with n Buli, reacted with iodomethane to give 1 . Compound 1 has been cha
Autor:
Iyer S. Saranathan, Bala Manimaran, Jayshree Murthy, Md. Munkir Hossain, C. V. V. Satyanarayana, Pradeep Mathur, Rupa Shanbag, Mohan M. Bhadbhade
Publikováno v:
Journal of Organometallic Chemistry. 490:173-178
The methylene-bridged, mixed-chalcogen compounds Fe-2(CO)(6)(mu-SeCH2Te) (1) and Fe-2(CO)(6)(mu-SCH2Te) (3) have been synthesised from the room temperature reaction of diazomethane with Fe2(CO)6(mu-SeTe) and Fe-2(CO)(6)(mu-STe), respectively. Compoun
Publikováno v:
IndraStra Global.
Bubbling acetylene gas slowly through a methanol solution of [(CO)(6)Fe-2{mu-SSe}] containing sodium acetate for 48 h at room temperature yields the double-butterfly complex mu-[ethane-1,1,2,2-tetra(selenido/sulfido)]bis[hexacarbonyldiiron(Fe - Fe)],
Publikováno v:
IndraStra Global.
Stirring at room temperature of [(CO)(6)Fe-2{mu-SeC(H)=C(CH2OH)Se}] with Pt(PPh3)(4) or Pt(C2H4)(PPh3)(2) in dichloromethane affords the mu(3)-Se-bridged mixed-metal cluster pentacarbonyl-1 kappa(3)C,2 kappa C,3 kappa C-mu(3)-selenido-1:2:3 kappa(3)S
Publikováno v:
IndraStra Global.
The diacetylenic adducts, Fe-2(CO)(6){mu-EC(H) = C(C = CMe)E'} (E = E' and E not equal E'; E, E' = S, Se, Te) (1-8) have been obtained from the room temperature stirring of Fe-2(CO)(6)(mu-EE') with HC = CC = CMe in methanol solvent containing sodium
Autor:
MATHUR, P, DASH, AK, HOSSAIN, MM, SATYANARAYANA, CVV, RHEINGOLD, AL, LIABLESANDS, LM, YAP, GPA
Publikováno v:
IndraStra Global.
Room temperature reaction of [(CO)(6)Fe-2{mu-SeC(H)=C(C=CR)Se}], with the dimetallic species, Cp2Mo2(CO)(4) and Co-2(CO)(8), afforded the adducts [(CO)(6)Fe2Se2(mu-HC=C(CCR)}Cp2Mo2(CO)(4)] (R = Me, 1; R = Bu-n, 2) and [(CO)(6)Fe2Se2{mu-HC=C(CCR))Co-2
Publikováno v:
IndraStra Global.
From the room temperature reaction of (CO)(9)Fe-3(mu(3)-Se)(2) or (CO)(6)Fe-2(mu-Se-2) with diazomethane, four products were isolated; {(CO)(3)Fe(mu-CH2)Se}(2) (1), (CO)(6)Fe-2(mu-SeCH3)(2) (2), (CO)(6)Fe-2(mu-SeCH2Se) (3) and (CO)(6)Fe-2(mu-SeCH2CH2
Autor:
Aswini K. Dash, Yu-Sheng Chen, Pradeep Mathur, S. Narasinga Rao, Elizabeth M. Holt, Md. Munkir Hossain
Publikováno v:
IndraStra Global.
Stirring of (CO)(6)Fe-2(mu-SSe) and phenylacetylene in methanol at room temperature for 16 h yielded the double butterfly complex [{(Co)(6)Fe2SSe}(2){mu-C(H)-C(Ph)}]. Compound [{(CO)(6)Fe2SSe}(2){mu-C(H)-C(Ph)}] was characterized by IR and H-1 and C-